Stimuli-responsive
fluorescent materials have recently been developed
and employed as fluorescent security inks for applications in the
fields of high-level security protection and multi-anticounterfeiting
because they can provide extra security features by switching luminescence
outputs in response to external stimuli. However, conventional stimuli-responsive
fluorescent inks are generally limited to unicolor or dual-color fluorescent
response behaviors in monotonous stimuli mode, resulting in being
comparatively less effective for advanced anticounterfeiting applications.
Herein, we report a new strategy for constructing a dual stimuli-responsive
multicolor security ink, which is based on the integration of the
near-infrared (NIR) light-responsive orthogonal three-primary-color
luminescence properties of upconversion nanoparticles and pH-sensitive
color-changing behavior of thymolphthalein dye. Unlike most other
invisible security inks, this new dual stimuli-responsive security
ink can realize visualization of hidden information. The information
recorded by this ink is initially visible under natural light and
then spontaneously becomes invisible within several tens of seconds.
The feature of disappearance in seconds allows customers to check
and correct concealed information before hiding it. In addition, upon
pH stimulation, the concealed information can be reversibly interconverted
between visible and invisible states. Meanwhile, upon ternary NIR
quadrature excitation (808/980/1560 nm), the information can emit
intense green, blue, and red fluorescence, respectively. More importantly,
the information printed with the security ink exhibits robust stability
against various chemical treatments, which demonstrates great potential
for practical applications in advanced anticounterfeiting.
To help retailers gain consumers’ trust, many studies have investigated antecedents of consumer trust. However, distrust, a concept closely related to trust, has attracted only sporadic research attention. As a result, whether factors that increase consumer trust can eliminate consumer distrust is unclear. To deepen understanding of trust and distrust, this study applies the critical incident technique to identify and compare the antecedents of trust and distrust of Chinese consumers. The results show that the antecedents of distrust differ from those of trust, indicating different formulation mechanisms of both. Therefore, on the one hand, retailers should pay attention to increasing consumer trust, and on the other hand, they should develop marketing activities to reduce consumer distrust.
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