The incorporation of a monolayer subsurface B into the Ni catalyst results in a corrugated Ni top surface and the activation of toluene is significantly promoted on B–Ni.
The technological settings of a modified sol-gel method for preparation of highly fine homogeneous powder Ca 2 CuO 3 doped with uranium 238 (x=0−0.05) is presented. The analysis of structure, purity of phases and the justification for the role of uranium in the given compounds are provided together with almost complete classification of observed optical phonons by means of the Raman, IR measurements and ab initio calculation. The significant reduction in particle size was achieved by doping and the strong correlation between resistivity and doping concentration was observed and explained using the phonon-assisted electron hopping conduction model. The persistence of covalent insulation state in all compounds is a key feature of this class of compounds.
Hard magnetic strontium hexaferrite SrFe
12
O
19 nanoparticles were synthesized by the sol–gel hydrothermal method. The factors affecting the synthesized process, such as the mole proportion of the reactants, pH, temperature, the hydrothermal conditions and the calcination process, have been investigated. The crystal structures of these materials were refined by Rietveld method. The obtained materials have single crystal phase, equal nano-size, plate shape and high anisotropy. The high magnetic coercivity of 6.3 kOe with the magnetization at 11.1 kOe of 66 emu
g
−1 at room temperature was observed for the strontium hexaferrite nanoparticles. For other nanoparticles (SrLn
x
Fe
12-x
O
19 and SrFe
12
O
19/CoFe
2
O
4) synthesized on the basis of SrFe
12
O
19 the complex completion of the crystal structure distortion and the interaction between magnetic phases were observed.
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