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The near-Earth carbonaceous asteroid (162173) Ryugu is expected to contain volatile chemical species that could provide information on the origin of Earth’s volatiles. Samples of Ryugu were retrieved by the Hayabusa2 spacecraft. We measure noble gas and nitrogen isotopes in Ryugu samples, finding they are dominated by pre-solar and primordial components, incorporated during Solar System formation. Noble gas concentrations are higher than those in Ivuna-type carbonaceous (CI) chondrite meteorites. Several host phases of isotopically distinct nitrogen have heterogeneous abundances between the samples. Our measurements support a close relationship between Ryugu and CI chondrites. Noble gases produced by galactic cosmic rays, indicating ~5 Myr exposure, and from implanted solar wind, record the recent irradiation history of Ryugu after it migrated to its current orbit.

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Northwest Africa (NWA) 11042 is a heavily shocked achondrite with mediumgrained cumulate textures. Its olivine and pyroxene compositions, oxygen isotopic composition, and chromium isotopic composition are consistent with L chondrites. Sm-Nd dating of its primary phases shows a crystallization age of 4100 AE 160 Ma. Ar-Ar dating of its shocked mineral maskelynite reveals an age of 484.0 AE 1.5 Ma. This age coincides roughly with the breakup event of the L chondrite parent body evident in the shock ages of many L chondrites and the terrestrial record of fossil L chondritic chromite. NWA 11042 shows large depletions in siderophile elements (<0.019CI) suggestive of a complex igneous history involving extraction of a Fe-Ni-S liquid on the L chondrite parent body. Due to its relatively young crystallization age, the heat source for such an igneous process is most likely impact. Because its mineralogy, petrology, and O isotopes are similar to the ungrouped achondrite NWA 4284 (this work), the two meteorites are likely paired and derived from the same parent body. Sample