(16) Psyche is the largest M-type asteroid in the main belt and the target of the NASA Discovery-class Psyche mission. Despite gaining considerable interest in the scientific community, Psyche's composition and formation remain unconstrained. Originally, Psyche was considered to be almost entirely composed of metal due to its high radar albedo and spectral similarities to iron meteorites. More recent telescopic observations suggest the additional presence of low-Fe pyroxene and exogenic carbonaceous chondrites on the asteroid's surface. To better understand the abundances of these additional materials, we investigated visible near-infrared (0.35–2.5 μm) spectral properties of three-component laboratory mixtures of metal, low-Fe pyroxene, and carbonaceous chondrite. We compared the band depths and spectral slopes of these mixtures to the telescopic spectrum of (16) Psyche to constrain material abundances. We find that the best matching mixture to Psyche consists of 82.5% metal, 7% low-Fe pyroxene, and 10.5% carbonaceous chondrite by weight, suggesting that the asteroid is less metallic than originally estimated (∼94%). The relatively high abundance of carbonaceous chondrite material estimated from our laboratory experiments implies the delivery of this exogenic material through low velocity collisions to Psyche's surface. Assuming that Psyche's surface is representative of its bulk material content, our results suggest a porosity of 35% to match recent density estimates.

Remote spectral characterization of near-Earth asteroids (NEAs) relies on laboratory spectral calibration to constrain their surface composition, including mineral chemistry and relative mineral abundances. Often these calibrations are based on fine meteorite powders that are representative of regolith observed on large NEAs such as (433) Eros. However, spacecraft observations of smaller NEAs such as (25143) Itokawa, (101955) Bennu, and (162173) Ryugu show surfaces devoid of a thick layer of regolith and instead find variegated landscapes with millimeter-sized particles to meter-scale boulders. Here we present the results of a laboratory study to understand the effects of grain size on the spectral properties of meteorites and how this can impact ground-based characterization of NEAs. Our study focuses on ordinary chondrites (H, L, LL) and HED meteorites, as they comprise ∼90% of all meteorites that fall on Earth. Compared to ordinary chondrites, the spectral band parameters of HED meteorites are less affected by changing grain size. Among the ordinary chondrites, LL chondrites are least affected, but the spectral band parameters and mineral chemistries and abundances for H and L chondrites are most affected by changing grain size. Grain size does not seem to have any significant effect on the taxonomic classification of our meteorite spectra. We also used the Hapke model to investigate trends in single-scattering albedo as a function of grain size and present equations to recover the grain size from a spectrum.

Metal-rich near-Earth asteroids (NEAs) represent a small fraction of the NEA population that is mostly dominated by S- and C-type asteroids. Because of this, their identification and study provide us with a unique opportunity to learn more about the formation and evolution of this particular type of bodies, as well as their relationship with meteorites found on Earth. We present near-infrared (NIR) spectroscopic data of NEAs 6178 (1986 DA) and 2016 ED85. We found that the spectral characteristics of these objects are consistent with those of metal-rich asteroids, showing red slopes, convex shapes, and a weak pyroxene absorption band at ∼0.93 μm. The compositional analysis showed that they have a pyroxene chemistry of Fs40.6±3.3Wo8.9±1.1 and a mineral abundance of ∼15% pyroxene and 85% metal. We determined that these objects were likely transported to the near-Earth space via the 5:2 mean motion resonance with Jupiter. Asteroid spectra were compared with the spectra of mesosiderites and bencubbinites. Differences in the NIR spectra and pyroxene chemistry suggest that bencubbinites are not good meteorite analogs. Mesosiderites were found to have a similar pyroxene chemistry and produced a good spectral match when metal was added to the silicate component. We estimated that the amounts of Fe, Ni, Co, and the platinum group metals present in 1986 DA could exceed the reserves worldwide.

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