We report the use of transition metal nanoparticles (Ni or Co) to longitudinally cut open multiwalled carbon nanotubes in order to create graphitic nanoribbons. The process consists of catalytic hydrogenation of carbon, in which the metal particles cut sp(2) hybridized carbon atoms along nanotubes that results in the liberation of hydrocarbon species. Observations reveal the presence of unzipped nanotubes that were cut by the nanoparticles. We also report the presence of partially open carbon nanotubes, which have been predicted to have novel magnetoresistance properties.(1) The nanoribbons produced are typically 15-40 nm wide and 100-500 nm long. This method offers an alternative approach for making graphene nanoribbons, compared to the chemical methods reported recently in the literature.
Metal‐dielectric Au‐Co‐SiO2 magnetoplasmonic nanodisks are found to exhibit large magneto‐optical activity and low optical losses. The internal architecture of the nanodisks is such that, in resonant conditions, the electromagnetic field undertakes a particular spatial distribution. This makes it possible to maximize the electromagnetic field at the magneto‐optically active layers and minimize it in the other, optically lossy ones.
Surface plasmon polariton ͑SPP͒ excitation effects on the magneto-optical ͑MO͒ activity of Au capped Ag/Co/Ag trilayers are studied as a function of Co thickness. An enhancement of the transverse MO Kerr signal under SPP excitation as compared with that obtained without SPP excitation is measured with a maximum value of 150 times obtained for the trilayer with 8 nm Co. Such enhancement on the magneto-optical activity due to SPP excitation is also five times higher than that obtained in Au/Co/Au trilayers in similar conditions. The lower optical absorption in the studied range and the sharper plasmon resonance of Ag vs Au are responsible for these values. On the other hand, magnetic field-induced SPP wavevector modulation ͑⌬k / k͒ SPP is studied for these trilayers and compared both with previous results in the Au/Co/Au system as well as with the theory. In the wavelength considered here, the obtained values are similar for both Ag-and Au-based structures and on the order of 10 −4 , pinpointing the role of the magnetic layer on the SPP wavevector modulation.
We show that the interaction between a plasmonic and a magnetoplasmonic metallic nanodisk leads to the appearance of magnetooptical activity in the purely plasmonic disk induced by the magnetoplasmonic one. Moreover, at specific wavelengths the interaction cancels the net electromagnetic field at the magnetoplasmonic component, strongly reducing the magneto-optical activity of the whole system. The MO activity has a characteristic Fano spectral shape, and the resulting MO inhibition constitutes the magneto-optical counterpart of the electromagnetic induced transparency.
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