In this paper, we study the wave transport and localization properties of novel aperiodic structures that manifest the intrinsic complexity of prime number distributions in imaginary quadratic fields. In particular, we address structure-property relationships and wave scattering through the prime elements of the nine imaginary quadratic fields (i.e., of their associated rings of integers) with class number one, which are unique factorization domains (UFDs). Our theoretical analysis combines the rigorous Green’s matrix solution of the multiple scattering problem with the interdisciplinary methods of spatial statistics and graph theory analysis of point patterns to unveil the relevant structural properties that produce wave localization effects. The onset of a Delocalization-Localization Transition (DLT) is demonstrated by a comprehensive study of the spectral properties of the Green’s matrix and the Thouless number as a function of their optical density. Furthermore, we employ Multifractal Detrended Fluctuation Analysis (MDFA) to establish the multifractal scaling of the local density of states in these complex structures and we discover a direct connection between localization, multifractality, and graph connectivity properties. Finally, we use a semi-classical approach to demonstrate and characterize the strong coupling regime of quantum emitters embedded in these novel aperiodic environments. Our study provides access to engineering design rules for the fabrication of novel and more efficient classical and quantum sources as well as photonic devices with enhanced light-matter interaction based on the intrinsic structural complexity of prime numbers in algebraic fields.

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