The as-prepared BT1.5TNs exhibits superior photocatalytic performance for RhB degradation due to Ti3+ doping.

In present work, a novel Nd@TiO2 Nanocomposite, synthesized successfully by a facile sol–gel method, reveals significant light-activated antibacterial activity. The X-ray diffraction (XRD), Raman spectroscopy and transmission electron microscopy (TEM) show the anatase phase and globular shape of Nd@TiO2. UV-vis diffuse reflectance spectroscopy and low temperature N2 adsorption (BET) indicate Nd0.02@TiO2 has the narrow band gap (3.0 eV) and a high specific surface area (121.1 m2·g-1). Furthermore, the prepared Nd@TiO2 exhibits unprecedented higher photocatalytic activity than P25 TiO2. In water, Nd@TiO2 has higher inactivation against Escherichia coli (E. coli) bacteria under simulated solar light irradiation 70 min than TiO2, and the highest antibacterial efficiency (91.5%) of E. coli was achieved on Nd0.02@TiO2.

ZIF-67@Ta2O5 graded hetero-structure material was designed and prepared using F-Ta2O5 as a raw material and Zeolite imidazole ester(ZIF-67) as framework structure material. The hetero-structure Ta2O5 and ZIF-67@Ta2O5 were annealing 6 hours at 900°C in nitrogen ambience. The photolysis properties of the Ta2O5 and ZIF-67@Ta2O5 materials as catalysts for photocatalytic decomposition of water to hydrogen were characterized. The results show that the heterogeneous composite structure formed by cobalt-tantalum oxide and tantalum pentoxide can significantly improve the hydrogen production performance of tantalum pentoxide samples, and the properties of samples obtained under nitrogen atmosphere are better. Among them, the N-50 sample (F-Ta2O5 is 50mg, Cobalt nitrate dosage is 6ml, annealing 6 hours at 900°C in nitrogen ambience) has the best hydrogen production performance, and the hydrogen production rate is 116μmol/g/h.