Linear regression methods can be used to quantify geological controls on baseflow index (BFI). This is illustrated using an example from the Thames Basin, UK. Two approaches have been adopted. The areal extents of geological classes based on lithostratigraphic and hydrogeological classification schemes have been correlated with BFI for 44 'natural' catchments from the Thames Basin. When regression models are built using lithostratigraphic classes that include a constant term then the model is shown to have some physical meaning and the relative influence of the different geological classes on BFI can be quantified. For example, the regression constants for two such models, 0.64 and 0.69, are consistent with the mean observed BFI (0.65) for the Thames Basin, and the signs and relative magnitudes of the regression coefficients for each of the lithostratigraphic classes are consistent with the hydrogeology of the basin. In addition, regression coefficients for the lithostratigraphic classes scale linearly with estimates of log 10 hydraulic conductivity for each lithological class. When a regression is built using a hydrogeological classification scheme with no constant term, the model does not have any physical meaning, but it has a relatively high adjusted R 2 value and because of the continuous coverage of the hydrogeological classification scheme, the model can be used for predictive purposes. A model calibrated on the 44 'natural' catchments and using four hydrogeological classes (low permeability surficial deposits, consolidated aquitards, fractured aquifers and intergranular aquifers) is shown to perform as well as a model based on a hydrology of soil types (BFIHOST) scheme in predicting BFI in the Thames Basin. Validation of this model using 110 other 'variably impacted' catchments in the Basin shows that there is a correlation between modelled and observed BFI. Where the observed BFI is significantly higher than modelled BFI the deviations can be explained by an exogenous factor, catchment urban area. It is inferred that this is may be due influences from sewage discharge, mains leakage, and leakage from septic tanks.

Understanding the processes controlling groundwater-surface water interaction is essential for effective resource management and for protecting sensitive ecosystems. Through intensive monitoring of Chalk groundwater, surface water, and shallow gravel groundwater along a river bank and below the river, using a combination of hydrochemical and hydrophysical techniques a complex pattern of interactions has been elucidated. The river is broadly in hydraulic contact with the river bed and adjacent gravels and sands (although with local variability), but these sediments are mainly hydraulically separate from the underlying Chalk at the site. The relationship between the river and underlying alluvium is variable, involving components of groundwater flow both parallel and transverse to the river and with both effluent and influent behaviour seen. The degree of groundwater-surface water interaction within the hyporheic zone at this site seems to be controlled by a number of factors including lithology, topography, and the local groundwater flow regime. While the gravel aquifer is significant in controlling groundwater-surface water interaction, its importance as a route for flow down the catchment is likely to be modest compared with river discharge.

Groundwater ecosystems remain poorly understood yet may provide ecosystem services, make a unique contribution to biodiversity and contain useful bio-indicators of water quality. Little is known about ecosystem variability, the distribution of invertebrates within aquifers, or how representative boreholes are of aquifers. We addressed these issues using borehole imaging and single borehole dilution tests to identify three potential aquifer habitats (fractures, fissures or conduits) intercepted by two Chalk boreholes at different depths beneath the surface (34 to 98 m). These habitats were characterised by sampling the invertebrates, microbiology and hydrochemistry using a packer system to isolate them. Samples were taken with progressively increasing pumped volume to assess differences between borehole and aquifer communities. The study provides a new conceptual framework to infer the origin of water, invertebrates and microbes sampled from boreholes. It demonstrates that pumping 5 m3 at 0.4–1.8 l/sec was sufficient to entrain invertebrates from five to tens of metres into the aquifer during these packer tests. Invertebrates and bacteria were more abundant in the boreholes than in the aquifer, with associated water chemistry variations indicating that boreholes act as sites of enhanced biogeochemical cycling. There was some variability in invertebrate abundance and bacterial community structure between habitats, indicating ecological heterogeneity within the aquifer. However, invertebrates were captured in all aquifer samples, and bacterial abundance, major ion chemistry and dissolved oxygen remained similar. Therefore the study demonstrates that in the Chalk, ecosystems comprising bacteria and invertebrates extend from around the water table to 70 m below it. Hydrogeological techniques provide excellent scope for tackling outstanding questions in groundwater ecology, provided an appropriate conceptual hydrogeological understanding is applied.

analysis of the data shows (i) that the porosity distributions for the Upper Chalk of the Southern and Thames & Chilterns regions are indistinguishable, (ii0 that the porosity distributions for the middle and Lower Chalk of the East Anglian region are indistinguishable, and (iii) that the porosity distributions for each of the gross stratigraphical units from all other regions are statistically discrete. Porosities range from 3.3% to 55.5%, with a mean porosity of 34.0%. Dry densities range from 1210 kg/m3 to 2510 kg/m3, with a mean dry density of 1790 kg/m3. In a given region there is a trend of increasing porosity from Lower to Middle to Upper Chalk. There are systematic variations in porosity between the regions. There is a trend of increasing porosity from the Northern England region to the Southern England region, to the Thames & Chilterns region, to East Anglia. No significant systematic variations in porosity-depth gradients were observed. Chalk porosity-depth gradients are typically high, of the order of-0.07 to-0.1 porosity per cent per metre.

The Water Framework Directive (WFD) identifies diffuse pollution as a long-term threat to water quality. Farming contributes significantly to this pollution. There is a clear need for mitigation measures and assessment of their efficacy. Accordingly, Demonstration Test Catchments (DTCs) have been established in England to test the effectiveness of changes in agricultural practice on river water quality and ecology. However, the presence of groundwater in these hydrological systems implies a wide range of travel times for pollutants from source to receptor. Unless flow routes are better characterised, it will be difficult to gauge the success of control measures in the short-term.Using 3D modelling and supplementary hydrochemical information, this study considers the hydrogeology of several sub-catchments in the Avon DTC, southern England. Data suggest that groundwater ages >25 years exist in parts of the catchments; clearly observations like these must be used to judge the likely effectiveness of targeted control measures. The revealed hydrogeological complexity of the Avon catchment is unlikely to be unique, so the techniques described here should be applicable to other lowland river systems with moderate-to-high baseflow indices (>0.5). To support the WFD, groundwater conceptual models should inform the design of effective measures for diffuse pollution mitigation..