For the first time, fullerene (C60) was used to enhance the photogenerated electron–hole separation of MOFs as a catalyst and showed high catalytic activity in the photocatalytic oxidation of thioether in air.

In this work, CdS@NH2-MIL-125 nanocomposite as photocatalyst was successfully synthesized by forming a common boundary between CdS and NH2-MIL-125, via in situ a solvothermal strategy, and then the physicochemical properties...

Metal nanoparticles (NPs) stabilized by MOFs are very promising for catalysis, whereas introduction of C into MOFs has been very rarely used, and there was no report for their cooperative catalysis in organic syntheses. In this work, C @UiO-67 was synthesized by a one-pot method, so that C is uniformly distributed on UiO-67 in molecular form. Pd NPs coordinating with C have been successfully embedded into the framework. The obtained multifunctional C Pd @UiO-67 catalyst exhibits remarkable synergistic catalytic activity in cascade reactions under mild conditions, where UiO-67 affords Lewis acidity and C Pd offers higher hydrogenation activity relative to solely Pd NPs.

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