Nanosilica powder produced from rice husk ash (RHA) via NaOH treatment has particle size in the range of 10-20 nm as revealed by transmission electron microscopy (TEM). The inhibitive action of nanosilicate from RHA on the corrosion of carbon steel SAE1045 in 0.5M HCl solution was studied using weight loss and potentio dynamic polarization methods. Result shows that the inhibition efficiency was increased with increasing of the inhibitor concentration. Nanosilicate was tremendously effective on carbon steel; exhibiting high inhibition efficiency attained 99%at optimum concentration of 175 ppm. Pitting was not observed on surface of carbon steel when the inhibitor was present. This finding was confirmed from surface morphology by scanning electron microscopy (SEM).
The highly advance usage of an agricultural waste of rice husk ash (RHA) from Oryza sativa L. was developed by extracting the nanosilicate contained in RHA as a corrosion inhibitor for carbon steel in 0.5 M NaCl media. The corrosion measurement was studied using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), surface analysis, and adsorption isotherm study. The extracted nanosilicate powder from RHA was analyzed using Fourier Transform Infrared Spectroscopy (FTIR) to identify the presence of functional groups (SiO 2 ), whereas X-ray diffraction (XRD) to identify the phase of silica from RHA. The particle size of nanosilicate was confirmed by transmission electron microscopy (TEM) and Zetasizer analysis, and the results show particle size of nanosilicate in the range of 5-10 nm. The maximum inhibition efficiency (IE%) is up to 88% in NaCl media. On the other hand, the inhibitor adsorption properties follow Temkin isotherm with mixed type of inhibition properties. Surface analysis on specimen that was treated with nanosilicate was smoother with fewer pits and pores than untreated specimen. In future perspectives, nanosilicate from RHA has a promising advantages and imminent applications for industries revolving with composites, biomedicine, and many more.
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