No abstract

The grate-kiln process is employed for sintering and oxidation of iron-ore pellets. In this process, a fuel (typically coal) is combusted with a large amount of excess air in a rotary kiln, and the high air-to-fuel ratio leads to significant NO x formation. The current Article is an assessment of NO x reduction measures that have been tested in pilot-scale and in full-scale by the Swedish iron-ore company Luossavaara-Kiirunavaara Aktiebolag (LKAB). The results show that the scaling between the full-scale kiln and the pilot-scale kiln is crucial, and several primary measures that reduce NO x significantly in pilot-scale achieve negligible reduction in full-scale. In the investigated full-scale kiln, thermal NO x formation is efficiently suppressed and low compared with the NO formation from the fuel-bound nitrogen (especially char-bound nitrogen). Suppressing the NO formation from the char-bound nitrogen is difficult due to the high amounts of excess air, and all measures tested to alter mixing patterns have shown limited effect. Switching to a fuel with a lower nitrogen content is efficient and probably necessary to achieve low NO x emissions without secondary measures. Simulations show that replacing the reference coal with a biomass that contains 0.1% nitrogen can reduce NO x emissions by 90%.

The purpose of this study was to investigate the merging behavior of small-scale buoyant flames that might be representative of flames from a leaf in a shrub. Zirconia felt pads soaked in n-heptane were suspended on thin rods and spaced both horizontally and vertically. Time-dependent video images from flames from two-pad and three-pad configurations were analyzed to determine merging probability, combined flame characteristics (height, area, and width), and changes in burn time. Correlations of these combined flame characteristics were developed based on horizontal and vertical spacing between the pads. Merging probability correlated with an exponential function that was quadratic in horizontal and/or vertical spacing. Flame heights corrected for vertical inter-pad spacing showed a maximum increase of 50% over single flame heights, and were correlated with an exponential decay function. Flame areas increased by a maximum of 34%, but on average were relatively constant. Corrected flame widths for the merged flames increased by as much as 55% in some configurations, but decreased by up to 73% in other configurations. Burn times for upper pads decreased when there was no horizontal spacing. The limited flame growth observed in these non-overlapping configurations in the horizontal dimension imply that overlapping configurations seem to be necessary for significant flame growth.