A suitable optimized digestion method for lipsticks and powders for the analysis of As, Hg, Cd, Cr, Ni and Pb by Hydride Generation Atomic Absorption Spectrophotometry (HG-AAS), Cold Vapor Atomic Absorption Spectrophotometry (CV-AAS) and Flame Atomic Absorption Spectrophotometry (FAAS) was developed using common acid digestion methods enhanced by the use of Triton X-100. The three acid digestion methods used in this study were Method A (nitric acid and hydrogen peroxide), Method B (nitric acid and hydrochloric acid) and Method C (nitric acid, hydrochloric acid and hydrogen peroxide). Triton X-100 was added to each of these and the effects were studied. The acid digestion method that was determined to be the most suitable and efficient for lipsticks and powders was Method A-1 (nitric acid and hydrogen peroxide with 5% Triton X-100 at 95 °C for 3 h). The range of percentage recoveries obtained were; powders (98.50% to 92. 61%) and lipsticks (100.96% to 99.41%) for As, Cd, Cr, Pb, Hg and Ni. The addition of Triton X-100 significantly improved the efficiency of the method. Triton X-100 improves the efficiency of acid digestion of fatty hydrophobic samples by dispersing the sample throughout the acid digestant.

Arsenic contamination in chicken is a cause of concern because of the potential health problems that may arise. In Trinidad and Tobago, chicken consumption averages about 53.8 kg per person per year, and chicken accounts for 85% of all the meat consumed locally. Fourteen chicken samples of imported, locally grown, and local organically farmed chickens were obtained from poultry depots and local supermarkets and were analyzed in triplicate. The concentration of total arsenic in the imported chicken ranged from below the method detection limit (MDL) to 512.50 μg/kg, and the concentration in the locally produced chicken ranged between <MDL and 516.44 μg/kg. The estimated concentration of inorganic arsenic (iAs) in the imported chickens ranged between <MDL and 333.12 μg/kg, whereas in local chicken it ranged between <MDL and 335.68 μg/kg. The estimated daily intake (EDI) of iAs varies between 0 and 0.72 μg/kg/day. Five of the samples evaluated exceeded the tolerable limit of 0.3 μg/kg of body weight per day as set by the U.S. Environmental Protection Agency. HIGHLIGHTS