Dirk Rieger scite author profile

The metal‐coordinated hydrogen isocyanide in [Cr(CO)5CNH] proved to be an ideal hydrogen‐bond former. Its discrete adducts with ethers and cyano complexes are surprisingly stable and some are sublimable (1, [Cr] = Cr(CO)5). According to IR, X‐ray structure, and 15NMR investigations, strong N‐H…︁O hydrogen bonds are present. The shortest bonds are found for 2 ([Fe] = FeCp(diphos)) and 3. In 3, the N‐H…︁N bonds are symmetrical. diphos = bis(diphenylphosphino)ethane.

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The supercomplex nature of Buff's ‘ferrocyanäthyl’. First example of a homoleptic hydrogen isocyanide (CNH) metal complex

Rieger¹,

Hahn²,

Fehlhammer³

1990

J. Chem. Soc., Chem. Commun.

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Dirk Rieger

Octahedro octahedra and tetrahedra. II. Tetra- to heptanuclear carbonyl(cyano)chromato, -molybdato and -tungstato complexes of 3d metals

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Molecular and Ionic Hydrogen Isocyanide (CNH) Adducts with N‐H…︁O‐ and “Super‐Short” N‐H…︁N‐Hydrogen Bridges: Metal‐Stabilized Hydrogen Bisisocyanides

The supercomplex nature of Buff's ‘ferrocyanäthyl’. First example of a homoleptic hydrogen isocyanide (CNH) metal complex

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