A new non-contact and non-destructive optical scanning instrument provided a large number of high-precision measurements of thermal conductivity tensor components in samples of sedimentary and impact rocks, as well as new insights into interrelations between thermal conductivity and other physical properties. More than 800 core samples (dry and fluid-saturated) of sedimentary rocks from different Russian oil-gas deposits and impact rocks from the well ''No¨rdlingen 1973'' drilled in the Ries impact structure (Germany) were studied using optical scanning technology. It was established that the thermal conductivity parallel to the stratification is more informative for petrophysical investigations than the thermal conductivity perpendicular to the layering. Different approaches were developed to estimate porosity, permeability, pore space geometry, and matrix thermal conductivity with a combination of thermal conductivity measurements in dry and fluid-saturated samples and mathematical modelling. These approaches allow prediction of the rock porosity and permeability and their spatial distribution along a well using thermal conductivity measurements performed with the optical scanning instrument directly applied to cores. Conditions and constraints for using Lichtenecker-Asaad's theoretical model for the estimation of porosity and thermal conductivity of sedimentary rocks were determined. A correlation between thermal conductivity and acoustic velocity, porosity, density, and electric resistivity of impact rocks was found for different rock types. New relationships between permeability, electrical and thermal conductivity found for sedimentary rocks are described.

Abstract-Physical properties were determined in a first step on post-impact tertiary limestones from the depth interval of 404-666 m of the Yaxcopoil-1 (Yax-1) scientific well, drilled in the Chicxulub impact crater (Mexico). Thermal conductivity, thermal diffusivity, density, and porosity were measured on 120 dry and water-saturated rocks with a core sampling interval of 2-2.5 m. Nondestructive, non-contact optical scanning technology was used for thermal property measurements including thermal anisotropy and inhomogeneity. Supplementary petrophysical properties (acoustic velocities, formation resisitivity factor, internal surface, and hydraulic permeability) were determined on a selected subgroup of representative samples to derive correlations with the densely measured parameters, establishing estimated depth logs to provide calibration values for the interpretation of geophysical data. Significant short-and long-scale variations of porosity (1-37%) turned out to be the dominant factor influencing thermal, acoustic, and hydraulic properties of this post impact limestone formation. Correspondingly, large variations of thermal conductivity, thermal diffusivity, acoustic velocities, and hydraulic permeability were found. These variations of physical properties allow us to subdivide the formation into several zones. A combination of experimental data on thermal conductivity for dry and water-saturated rocks and a theoretical model of effective thermal conductivity for heterogeneous media have been used to calculate thermal conductivity of mineral skeleton and pore aspect ratio for every core under study. The results on thermal parameters are the necessary basis for the determination of heat flow density, demonstrating the necessity of dense sampling in the case of inhomogeneous rock formations.

No abstract

S U M M A R YThe results of thermal property measurements on cores from the scientific well Yaxcopoil-1 (1511 m in depth) drilled in the Chicxulub impact structure (Mexico) are described. The thermal conductivity, thermal diffusivity, volumetric heat capacity, thermal anisotropy coefficient, thermal heterogeneity factor, and, in addition, porosity and density were measured on 451 dry and water-saturated cores from the depth interval of 404-1511 m. The acoustic velocities were determined on a subgroup of representative samples. Significant vertical short-and long-scale variations of physical properties related to the grade of shock-thermal metamorphism and correlations between thermal and other physical properties are established. Rocks of the post-impact and impact complexes differ significantly in heterogeneity demonstrating that the impact complex has larger micro-heterogeneity on sample scale. The pre-impact rocks differ essentially from the impact and post-impact rocks in the thermal conductivity, thermal diffusivity, density and porosity. The thermal anisotropy of rocks of all structurallithological complexes is very low (K = 1.02 . . . 1.08), which is similar to the situation in the Puchezh-Katunk and Ries impact structures. Correlations are established between the thermal conductivity and elastic wave velocities measured in laboratory. For limestone-calcarenites, the thermal conductivity (λ) can be calculated from the compressional wave velocity (V p ) using the formula λ = 0.346 V p + 0.844, and for dolomite-anhydrites this relation has the form λ = 0.998 V p + 1.163 [for λ in W (m K) −1 and V p in km s −1 ]. These correlations are used for downscaling of the sonic velocities to the decimetre scale. The effective medium theory is applied to invert the matrix thermal conductivity and pore/crack geometry from the thermal conductivity measured on the studied samples. Representative experimental data on the thermal properties for all lithological groups encountered by the Yaxcopoil-1 well essentially extend an existing database on the thermal properties of rocks of impact structures and can be used for determination of the heat flow density, interpretation of temperature logging data, theoretical modelling of heat and mass transfer processes and constructing thermal models of the Chicxulub impact structure as well as for the lithological interpretation. The research results confirm the necessity of dense sampling for the thermal property measurements to obtain reliable results in petrophysical and geothermal investigations of impact structure formations.

No abstract