This study investigates the ability of water-soluble detergent capsules to effectively release microplastics from their composition. A total of 39 different brands of water-soluble capsulated detergents were tested, 20 of them for washing machines and 19 for dishwashers, from four different countries in the EU, i.e., Spain, Portugal, Belgium, and Italy, as well as two different devices for microplastic recovery from laundry wastewater. Wastewater samples from all laundry capsules reported microplastics, mainly as entangled fibers from PET blankets, although none could be associated to capsule itself. This paper displays, through a calculated rate for microplastics, that fiber shedding from clothing maybe related to different detergent characteristics. Wastewater from both catching devices reported microplastics after their use, although samples from Guppyfriend bag displayed less fibers than those collected after the use of Cora Ball. Eventually, wastewater samples form dishwashing detergent capsules were much less contaminated with microplastics than those from laundry ones.
The worldwide production of plastics has been reported to grow from 335 million t in 2016 up to 348 million t in 2017, giving employment to over 1.5 million people in Europe. Plastic materials have changed our way of life because of their versatility, high durability and ability to be moulded in different shapes. For that reason, when discarded in the marine environment, plastics and especially microplastics can become an environmental hazard.This article describes the presence and abundance of microplastics in sandy beaches of a coastal city, Cartagena (southeast Spain), surrounding the Mar Menor coastal lagoon, an important tourist destination with also local activities, mainly fishery and agriculture. Microscopic observations and Fourier-transform infrared spectroscopy analyses displayed a total of 14 polymer families in the microplastic composition, mainly represented by low-density polyethylene (LDPE), high-density polyethylene, polyvinyl ester (PVE), polypropylene (PP), polystyrene, nylon (NYL) and polyester (PES). The extensive amount of polymer types together with an important variety of colours demonstrates the multiple origin of microplastics. LDPE in a film form proved to be a consequence of plastic greenhouses degradation, prone to cracking under environmental stress, because of their transportation through a northwest catchment down to the beach. Similarly, PVE used in naval composite structures as a primary resin proved to be higher in urban than in natural beaches because of the massive use of fishing boats and pleasure crafts. Littering and runoff were the main sources for other microplastic particles, mainly PP, NYL and PES.
This paper presents the results on the presence and characterization of microplastics (MP) in the gastrointestinal tract of gilthead seabream (Sparus aurata L.), a species of commercial interest from the Mar Menor coastal lagoon in Southeast Spain. This is the first time that microplastic ingestion is recorded in any species from this semi-enclosed bay. Stomach and intestine from a total of 17 specimens captured by local fishermen were processed, and microplastic particles and fibers found in all of them were displayed. Overall, 40.32% (279/692) of total isolated microparticles proved to be microplastics; i.e., <5 mm, as identified by FTIR spectroscopy. The average value by fish was 20.11 ± 2.94 MP kg−1, corresponding to average concentrations of 3912.06 ± 791.24 and 1562.17 ± 402.04 MP by kg stomach and intestine, respectively. Four MP forms were isolated: fiber (71.68%), fragment (21.15%), film (6.81%), and microbead (0.36%), with sizes ranging from 91 µm to 5 mm, an average of 0.83 ± 0.04 mm, and no statistically significant differences between mean sizes in stomach and intestine samples (F-test = 0.004; p = 0.936). Nine polymer types were detected, although most of fibers remained unidentified because of their small size, the presence of polymer additives, or closely adhered pollutants despite the oxidizing digestion carried out to eliminate organic matter. No significant correlation was found between main biological parameters and ingested microplastics, and high-density polyethylene (HDPE), low-density polyethylene (LDPE), polyethylene polypropylene (PEP), and polyvinyl (PV) were identified as the most abundant polymers. The average microplastic ingestion in this study area was higher than those reported in most studies within the Mediterranean Sea, and closely related to microplastic pollution in the surrounding area, although with a predominance of fiber form mainly due to fishery activities.
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