The present paper investigates the selective incorporation of preformed nanoparticles (hydrophobic Au-NP (2 nm); hydrophilic Au-NP (12 nm); hydrophobic CdSe-NP (1.9 nm); retrovirus-particles (approximately 30 nm)) into the interface of lipid vesicles and polymersomes via TEM and DLS investigations. Lipid membranes were made from N,N-dimethyl-N,N-dioctadecylammonium bromide (DODAB), di-oleoyl-phosphatidylcholine (DOPC), whereas polymersome-membranes were fabricated from the diblock copolymer poly-(butadiene-block-ethylenoxide). Stabilization of the final structures was achieved via sol/gel processes at the outside of the membranes, thus stabilizing the structure by a silicate shell. Whereas hydrophobic Au-NPs can be successfully embedded into the polymersome- and lipid-vesicle membranes, hydrophilic nanoparticles were found evenly distributed in the inner- and outer compartments of the vesicles and polymersomes. Significant effects such as size reduction, selective enrichment of all nanoparticles within only few polymersomes as well as budding effects of larger entities (i.e., viral particles) are described.

New synthetic methodologies towards hydrogen bonded supramolecular polymers are described. Focus is directed on synthetic work towards telechelics with hydrogen bonds either as side chain moieties or as endgroups. Physical ordering effects related to polymers and particles are discussed citing own and related work in ∼60 references.

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Summary: Polymersomes are self assembled vesicles composed of fully synthetic amphiphilic diblock copolymers. Many of their properties are similar to lipid vesicles, although with often higher thermal and mechanical stability within their curved membrane. Incorporation of nanosized objects into their hydrophilic interior or hydrophobic membrane represents an important method for functionalization of these biomimetic structures. We report on the embedding of hydrophobic gold nanoparticles (Au‐NPs) into polymersomes. Nanoparticles were prepared and incorporated into polymersomes made by standard film rehydration techniques from commercially available diblock copolymers. Characterization of the resulting structures was achieved by dynamic light scattering (DLS) and by TEM. Results on the preparation method, its influence on the polymersome stability and the application of these new membrane‐mimetics are reported.

Nanoclusters are used in a wide field of applications as building blocks in functional materials. In heterogeneous catalysis noble metal nanoclusters, such as Au, Pt, Rb and their intermetallic compounds are used on various oxide substrates for the conversion of matter. Au nanoclusters are used for converting CO to CO 2 . The chemical nature of the substrate is of importance for the redox reaction, and SiO 2 as well as TiO 2 can be used. The cluster size is crucial to obtain a maximum catalytic rate. In order to avoid coalescence of the noble metal nanoclusters and to achieve a maximum surface for the gas reaction, we use an SBA15-analogue, a porous amorphous SiO 2 with periodically arranged mesopores as a model system for a substrate material. The pores act as cages for the clusters and allow reactive gas flow.Complex characterisation of porous amorphous substrates for heterogeneous catalysis is essential for the development of novel efficient catalytic materials. Dependent of the growth process of the amorphous SiO 2 , SBA15 grows in different micromorphologies: a) continuous framework structure, b) as platelets or c) in connected roundish particles. Electron tomography is used as a tool for characterisation of the pore arrangement in these three sample geometries. In addition, CTEM and HRTEM are used for conventional imaging in two dimensions.The SiO 2 was prepared by sol-gel-processing using tetrakis(2-hydroxyethyl)orthosilicate as an ethylene glycol modified precursor and an amphiphilic molecule as the structure-directing agent. The mesoporous particles can be formed in a cooperative self-assembly process. The surfactant is then removed by subsequent annealing. The Au nanoclusters were deposited onto the SiO 2 by using tetrachlorogold-acid. The nanoclusters were characterised in two dimensions by HRTEM and HAADF. The results clarify the location of the Au nanoclusters inside of the mesoporous SiO 2 matrix.Dependent on the morphology of the SBA15 material, framework structure, platelets or roundish particles, we characterised the arrangement of the pores concerning diameter, arrangement and connectivity. For later applications it is of major importance to see whether the pores are straight or curved and whether they are open on two sides in order to allow gas flow. The structure of the pores was characterised in two dimensions by CTEM, HAADF and in three dimensions by electron tomography. The results show the differences in the pore structure dependent of the location in the sample, i.e. in the framework structure the difference between arms and the crosslinks. The results further allow a comparison of the pore structure within the framework structure, the platelets and the roundish particles.