Thermotropic nematic and chiral-nematic conjugated polymers consisting of polythiophene
and poly(p-phenylene) backbones carrying cyanobiphenyl and (−)-cholesterol as pendant groups were
synthesized and characterized as a new class of optical polymers. Spontaneous assembly of the conjugated
backbone was promoted by liquid crystalline mesomorphism on the part of the pendants, thereby allowing
uniaxially and helically aligned glassy films to be prepared for polarized photoluminescence (PL) studies.
In the thiophene series, the conjugated backbone was found to yield an absorption peak red-shifted from
those of the monomers and pendant groups. This permitted selective photoexcitation of the polythiophene
backbone to be accomplished. In the p-phenylene series, the conjugated backbone did not give rise to a
unique absorption peak. However, with excitation at the long wavelength edge of the absorption peak,
PL of the poly(p-phenylene) backbone was found to be 1 order of magnitude stronger than that of the
pendant cyanobiphenyl group. These ordered solid films produced significant degrees of linearly and
circularly polarized PL. Existing theories were found to be capable of representing the experimental
results with independently measured absorption coefficient, average refractive index, and optical
birefringence.
We report on fully reconfigurable CROWs with MEMS-tunable waveguides. Resonator-to-resonator and resonator-to-waveguide coupling are fully tunable. Resonance of a resonator is also widely tunable to cover its full FSR. The static power consumption per tunable coupler is below 10nW.
We report on a 16-core recirculating programmable photonic array based on MEMS-tunable directional couplers. The photonic array has a compact footprint (0.04mm2/cell) and negligible static power consumption. Waveguide-coupled single-ring resonators, CROWs, and add-drop filters are demonstrated.
We propose and demonstrate an ultra-low-power 3×3 unitary matrix multiplier with MEMS-based tunable couplers and phase shifters. The static power consumption and tuning energy per tuning element are less than 0.13 µW and 115 pJ, respectively.
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