Herein, we report the synthesis of
zeolite composites with core–shell
structure via a secondary growth technique and evaluation of their
catalytic performance in ethanol dehydration. In particular, SAPO-34
particles were functionalized by TPA+, followed by dispersion
in ZMS-5 or silicalite-1 to form SAPO-34@ZSM-5 and SAPO-34@silicalite-1
core–shell materials showed a hierarchical porous structure
consisting of both micropores and mesopores. The active sites in the
developed composites were found to have a mild acidity. Compared to
conventional zeolite catalysts in ethanol dehydration reaction, the
silicalite-1 composites. The novel core–shell materials showed
a hierarchical porous structure consisting of both micropores and
mesopores. The active sites in the developed composites were found
to have a mild acidity. Compared to conventional zeolite catalysts
in ethanol dehydration reaction, the core–shell SAPO-34@ZSM-5
improved the selectivity toward light olefins. In addition, our catalyst
test results revealed the enhancement in propylene and ethylene yield
over SAPO-34@ZSM-5 and SAPO-34@siliclite-1, respectively, as compared
to that of bare SAPO-34. An improved catalyst stability was also obtained
for the composite materials owing to their core–shell structure.
The improved catalytic performance reported in this study reveals
the potential utility of the zeolite composites with core–shell
structure in ethanol dehydration reaction.
In order to prepare engineering graduates with the written and oral communication skills needed in their professional careers a coordinated writing across the curriculum (WAC) program has developed in the chemical engineering department at the University of North Dakota. The students practice and develop their skills with writing assignments in both lecture and laboratory courses from the first‐year level through the fourth‐year capstone design course. The coordinated approach, especially in the four‐semester laboratory sequence, allows the students to develop their skills by building on communication experiences in previous courses. The WAC program at UND including writing and public speaking assignments is described.
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