A highly sensitive fluorescent turn-on probe specific for methylmercury species as well as inorganic mercury ions has been developed on the basis of mercury ion-promoted hydrolysis of a fluorescein-derived aryl vinyl ether.
Palladium pincer complexes composed of six-membered fused metallacycles have been synthesized directly
from 1,3-bis(2-pyridyloxy)benzene. The pincer complexes show
remarkably high turnover numbers and frequencies in the Heck
reaction.
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