Reduction of metal ions in dilute solutions is of great interest for purification of waste waters and process liquids. Hydrogen gas is a very attractive reductant, since its use gives no additional pollution. In this paper the reduction of chromate in a sulphuric acid medium has been studied. A new electrochemical cell, a GBC-ceI1, which is a combination of a gas-diffusion electrode in direct contact with a packed bed of carbon particles, is introduced. Hydrogen gas flows along the hydrophobic side of the gas-diffusion electrode and a chromate solution is pumped upwards through the bed. Experiments were carried out with H2SO 4 solutions initially containing 70 mol m -3 chromate at various temperatures, solution flow rates, H2SO 4 concentrations and bed thicknesses. Experimental results for the chromate reduction are described by an empirical relation. It has been found that the reduction of chromate is a first-order reaction in chromate and the apparent rate constant for the chromate reduction increases with decreasing chromate concentration and increasing temperature, H2SO 4 corlcentration and bed thicknesses and is practically independent of the flow rate of the solution. It is concluded that the new GBC-cell is very attractive for the reduction of chromate in dilute solutions and for industrial application on a large scale. List of symbols
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