The principal limitation of today's Ni-and Fe-based superalloys continues to be their susceptibility to intergranular degradation arising from creep, hot corrosion, and fatigue. Many precipitationstrengthened superalloys are also difficult to weld, owing to the formation of heat-affected zone (HAZ) cracks during postweld heat treatments (PWHTs). The present work highlights significant improvements in high-temperature intergranular degradation susceptibility and weldability arising from increasing the relative proportion of crystallographically ''special'' low-⌺ CSL grain boundaries in the microstructure. Susceptibility to intergranular degradation phenomena is reduced by between 30 and 90 pct and is accompanied by decreases in the extent and length of PWHT cracking of up to 50-fold, with virtually no compromise in mechanical (tensile) properties upon which the functionality of these specialty materials depends. Collectively, the data presented suggest that ''engineering'' the crystallographic structure of grain boundaries offers the possibility to extend superalloy lifetimes and reliability, while minimizing the need for specialized welding techniques which can negatively impact manufacturing costs and throughput.
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