In the present work, the effect of mineral aggregates (pumice stone and expanded clay aggregates) and chemical admixtures (superplasticizers and shrinkage reducing additives) as an alternative internal curing technique was investigated, to improve the properties of high-performance concrete. In the fresh and hardened state, concretes with partial replacements of Portland cement (CPC30R and OPC40C) by pulverized fly ash in combination with the addition of mineral aggregates and chemical admixtures were studied. The physical, mechanical, and durability properties in terms of slump, density, porosity, compressive strength, and permeability to chloride ions were respectively determined. The microstructural analysis was carried out by scanning electronic microscopy. The results highlight the effect of the addition of expanded clay aggregate on the internal curing of the concrete, which allowed developing the maximum compressive strength at 28 days (61 MPa). Meanwhile, the replacement of fine aggregate by 20% of pumice stone allowed developing the maximum compressive strength (52 MPa) in an OPC-based concrete at 180 days. The effectiveness of internal curing to develop higher strength is attributed to control in the porosity and a high water release at a later age. Finally, the lowest permeability value at 90 days (945 C) was found by the substitutions of fine aggregate by 20% of pumice stone saturated with shrinkage reducing admixture into pores and OPC40C by 15% of pulverized fly ash. It might be due to impeded diffusion of chloride ions into cement paste in the vicinity of pulverized fly ash, where the pozzolanic reaction has occurred. The proposed internal curing technology can be considered a real alternative to achieve the expected performance of a high-performance concrete since a concrete with a compressive strength range from 45 to 67 MPa, density range from 2130 to 2310 kg/m3, and exceptional durability (< 2000 C) was effectively developed.

Lately, the development of green chemistry methods with high efficiency for metal nanoparticle synthesis has become a primary focus among researchers. The main goal is to find an eco-friendly technique for the production of nanoparticles. Ferro- and ferrimagnetic materials such as magnetite (Fe3O4) exhibit superparamagnetic behavior at a nanometric scale. Magnetic nanoparticles have been gaining increasing interest in nanoscience and nanotechnology. This interest is attributed to their physicochemical properties, particle size, and low toxicity. The present work aims to synthesize magnetite nanoparticles in a single step using extracts of green lemon Citrus Aurantifolia residues. The results produced nanoparticles of smaller size using a method that is friendlier to health and the environment, is more profitable, and can be applied in anticorrosive coatings. The green synthesis was carried out by a co-precipitation method under variable temperature conditions. The X-ray Diffraction (XRD) and Transmission Electron Microscopy (TEM) characterization showed that magnetite nanoparticles were successfully obtained with a very narrow particle size distribution between 3 and 10 nm. A composite was produced with the nanoparticles and graphene to be used as a surface coating on steel. In addition, the coating’s anticorrosive behavior was evaluated through electrochemical techniques. The surface coating obtained showed good anticorrosive properties and resistance to abrasion.

This study investigates the corrosion mechanism on 100 wt.% MgO and 95 wt.% MgO with 5 wt.% nano-ZrO2 ceramic composites. First, MgO powder and powder mixtures (MgO + nano ZrO2) were uniaxially and isostatically pressed; then, they were sintered at 1650 °C. Corrosion by copper slag was studied in sintered samples. Physical properties, microstructure, and penetration of the slag in the refractory were studied. Results reveal that ZrO2 nanoparticles enhanced the samples’ densification, promoting grain growth due to diffusion of vacancies during the sintering process. Additionally, magnesia bricks were severely corroded, if compared with those doped with nano-ZrO2, mainly due to the dissolution of MgO grains during the chemical attack by copper slag.

In this work, we studied the phases in a Mg-Ti-O system using a 1:1 formulation of MgO:TiO2, mixing synthetic brucite of Mexican origin with TiO2 microparticles of high purity, with a heat treatment at 1100 °C for 1 h. Due to its valence electrons, TiO2 can contribute to the sintering process to improve density in MgO products. The raw materials and formulation by XPS and X-RD techniques were characterized. The results demonstrate the presence of different oxidation states in titania and the formation of different oxides in the Mg-Ti-O system when mixed and calcined at 1100 °C; additionally, we estimated the formation of vacancies in the crystal lattice during the transformation from hexagonal brucite to magnesia with a cubic structure centered on the faces. Its thermal behavior is indicated by the MgO-TiO2 phase diagram.

The deterioration of the refractory lining represents a significant problem for the smooth operation in the ferroalloys industry, particularly in the production of silicomanganese, due to the periodic requirements of substitution of the damaged refractory. Within this context, magnesia refractories are commonly employed in the critical zones of the furnaces used in silicomanganese production since the slag involved in the process has a basic character. The behavior of MgO–ZrO2 ceramic composites with different ZrO2 nanoparticles (0, 1, 3, and 5 wt.%) contents in the presence of silicomanganese slags is proposed in this manuscript. XPS, XRD and SEM–EDX were used to evaluate the properties of the ceramic composite against the silicomanganese slag. The static corrosion test was used to evaluate the corrosion of the refractory. Results suggest that corrosion is controlled by the change in slag viscosity due to the reaction between CaZrO3 and the melted slag. Besides, ZrO2 nanoparticles located at both triple points and grain boundaries act as a barrier for the slag advance within the refractory. The utilization of MgO refractories with ZrO2 nanoparticles can extend the life of furnaces used to produce silicomanganese.