The purpose of this study was to utilize NIR spectrometry to develop a novel method to detect and determine concentrations of different soils in dishwashing liquor during automatic dishwashing in real-time. If it is possible to differentiate between soils, this could be an opportunity to react specifically to them (e.g. by increasing the water temperature if fat components are not sufficiently emulsifying). The possibility of an automatic adaptation of the dishwashing process to different soils and soil levels could lead to a shorter, more environmentally friendly and cost-reducing process. In a first approach, an emulsion containing three soil types (oatmeal, egg-yolk and butterfat), water and detergent were used to develop NIR spectrometry prediction models. Transmittance spectra obtained with an Fourier transform near infrared (FT-NIR) spectrometer of testing standards of 76 automatic dishwashing cycles with seven samples per cycle were taken at various times during the main washing process for calibration (and validation) of the NIR spectrometry prediction models. The spectra were pretreated to develop NIR spectrometry prediction models for each type of soil using the partial least squares regression method with cross-validation. Overall, the coefficients of determination in cross-validation are R 2 > 0.92 for all NIR spectrometry prediction models developed. The results of the prediction models developed show that NIR spectrometry technology is a promising method to predict different levels of predefined soils in dishwashing liquor. The NIR spectrometry models were applied to an automatic dishwashing process with soiled dishes instead of emulsions containing soils to test their applicability. The resulting dishwashing process could be tracked in real-time by the dissolved soil concentrations, observed in the dishwashing liquor.
Washing machines should not only deliver good removal of stains, but also take care of the garments. Mechanical action produced by the washing machine has a twofold impact: It supports the removal of stains, but it also influences the structure of the textiles negatively and is, therefore, critical to textile care. Most washing machines are currently assessed by consumer organisations and political regulations, such as energy labelling, just for their washing properties. However, a long programme may provide a good washing performance, but might also damage the textiles more than a shorter programme. Test specimens assessing the mechanical impact are well known and published, for example, IEC PAS 62473:2007, however, they are rarely used. Reasons may be poor knowledge about their effectiveness in assessing the mechanical action and their reaction to different washing conditions, for example, load size, temperature and duration of the washing programme. It was the task of this study to verify this relationship and confirm that the thread removal fabric, as specified in IEC PAS 62473:2007, adds additional information to the assessment of a washing process. As a result of a wide variation of washing parameters, it could be shown that this test fabric is almost independent of the washing temperature, but shows a clear correlation with the load size and the length of the washing process. The thread removal specimens add valuable additional information concerning a relevant parameter of the washing process.
The aim of this study was to assess consumers' behavior in home hygiene with particular attention paid to hygiene in laundering. In this way, the applications of washing temperatures and detergents on textiles are evaluated. The data were obtained by using a questionnaire distributed at the “Action Day Sustainable Washing” arranged annually. The results of this sample provide a relevant insight into consumers' behavior: The consumer can generally estimate the level of infection risk coming from the different textiles. However, the majority of high risk textiles, such as cleaning cloths, are washed with detergents that do not contain any bleaching system. In view of the washing temperatures applied, the results indicate differences between the generations. This study clearly demonstrates the need for enhanced consumer communication regarding hygiene effectiveness in laundering.
Since the washing performance of household washing machines must comply with certain limit values, like the ecodesign requirements in Europe, the method of washing performance evaluation is crucial. Today, the washing performance is defined as an overall washing performance in IEC 60456:2010, constituting an calculation of the average sum of reflectance values of five different stain monitors. As a result, the different washing characteristics of each individual stain are totally neglected. This study investigates how the washing cycle affects the individual stains, when washing temperature, washing time and load size are varied systematically. The results show individual stains contribute differently to the overall washing performance. For a proper assessment of the washing performance, the individual stains’ contributions to the overall washing performance are required to be considered. A supplement of temperature sensitive stain monitors is suggested. E.g., as tea has a crucial contribution at higher temperature, this stain should have a higher influence in washing performance assessment when good bleaching or hygiene performance is requested.
An orange colored pigment identified as 2‐methoxy‐1,4‐naphthoquinone was separated and identified from the dark colored 0 to 15‐cm layer of Caribbean Vertisols. Extraction of the pigment was carried out by shaking the soil (> 2 mm) in CHCl3 (1:2) and decanting the supernatant liquid from which the pigment was purified by column chromatography and crystallization from ethanol. Eight kilograms of soil yielded 69 mg of the pigment. Identification of the pigment was determined using a combination of techniques including solubility tests, elemental analyses, melting point, ultraviolet, infrared, NMR, and mass spectroscopy. To the authors' knowledge, the isolation described herein is the first for a nonchlorophyllic pigment occurring in a chemically uncombined form in a tropical soil.
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