No abstract

Groundwater Circulation Wells (GCW) can be an effective in-situ remediation option allowing high mass recovery of contaminants in cases where contamination hotspots are located in saturated soil having low hydraulic conductivity. Traditional treatment options such as Pump&Treat, Air Sparging (AS)/Soil Vapor Extraction (SVE) and Multi Phase Extraction (MPE) typically require long operation times and significant costs for long-term plume management. GCWs induce meaningful changes in the groundwater flow introducing vertical flows both downward and upward, generating a “circulation cell”, which facilitates contaminant desorption from the soil. This study aims to understand the effects of a GCW on an aquifer in terms of both groundwater flow directions and water balance. A groundwater numerical model was built using MODFLOW-2005 to simulate the effect of the hydraulic parameters of the aquifer on the hydraulic circulation pattern of the GCW. The use of particle tracking simulated by MODPATH 7 showed the circulation cells and the impact on groundwater directions induced by different configurations of hydraulic parameters. The water flowing into the cell comes from both the injection well and the surrounding aquifer and the model shows how the hydraulic parameters of the aquifer, in particular the horizontal and vertical hydraulic conductivity, have a paramount influence in determining the shape and dimension of the circulation cell. A water mass balance analysis was carried out. It allowed to predict the groundwater flows exchanges between the GCW system and the surrounding aquifer, and to verify the sensitivity of the water budget to specific aquifer parameters. The results of this study are useful for further understanding the hydraulics of a GCW remediation system in order to support the design and to predict its performance.

In this study, wood mulch-based amendments were tested in a bench-scale microcosm experiment in order to assess the treatability of saturated soils and groundwater from an industrial site contaminated by chlorinated ethenes. Wood mulch was tested alone as the only electron donor in order to assess its potential for stimulating the biological reductive dechlorination. It was also tested in combination with millimetric iron filings in order to assess the ability of the additive to accelerate/improve the bioremediation process. The efficacy of the selected amendments was compared with that of unamended control microcosms. The results demonstrated that wood mulch is an effective natural and low-cost electron donor to stimulate the complete reductive dechlorination of chlorinated solvents to ethene. Being a side-product of the wood industry, mulch can be used in environmental remediation, an approach which perfectly fits the principles of circular economy and addresses the compelling needs of a sustainable and low environmental impact remediation. The efficacy of mulch was further improved by the co-presence of iron filings, which accelerated the conversion of vinyl chloride into the ethene by increasing the H2 availability rather than by catalyzing the direct abiotic dechlorination of contaminants. Chemical analyses were corroborated by biomolecular assays, which confirmed the stimulatory effect of the selected amendments on the abundance of Dehalococcoides mccartyi and related reductive dehalogenase genes. Overall, this paper further highlights the application potential and environmental sustainability of wood mulch-based amendments as low-cost electron donors for the biological treatment of chlorinated ethenes.