Solar distillation system depends on adhesion of water molecules inside the glass cover of solar stills. Regular glass surfaces are prone to adsorbing other unwanted compounds and in turn lower the percentage of recovery of pure distilled water. In this study, the production of purified distilled water was compared with and without the use of graphene-based surface modifiers. In areas where salt content is high, the first pass is still usually laden with salts. Hence, to improve adhesion of water and rejection of salts, both the inside glass cover surfaces and the metal absorber plates were modified using oxygen plasma treatment and graphene surface enhancement. Results showed a 48.9% improvement of distilled water recovery from an initial recovery of 2.90 L/m 2 per day to an average of 4.32 L/m 2 per day. In addition, the resulting distilled water passes the World Health Organization drinking water standards such as pH, electrical conductivity (EC), and salinity. The average reduction in EC was 96.52%, an average increase of 5.06% of pH, and an average reduction of salinity of 96.52%, all measured at the highest brine salinity of 5%. The reported value of EC was 23.33 µS/cm, a lowest and near-neutral pH of 6.85, and an average salinity of 12.10 ppm.
Particulate matter (PM) emissions from dairies and feedlot sources require regular emission factor update. Likewise, development of simple measurement technique to accurately measure pollution concentration is warranted to limit the impact of air pollution and take necessary actions. During June of 2020, a dairy facility from central Texas and a feedlot from the Texas Panhandle region, titled as Dairy B and Feedlot C, respectively, were chosen for measurement of PM emissions in the state of Texas to represent dairy facilities and cattle feedlots PM emission rates. Four stations, each assigned with an EPA-approved Federal Reference Method (FRM) sampler, Texas A&M University (TAMU) designed sampler and handheld non-FRM AEROCET (MET One Instruments) sampler for collocation, were selected within each sampling locations. Drones were also utilized mounted with a handheld AEROCET sampler for simultaneously sampling at a certain height. PM2.5 emissions of Dairy B were all below 24-h PM2.5 standard of 35 µg m−3 as specified by National Ambient Air Quality Standards (NAAQS) even at the 98th percentile. The PM ratio between regulated PM10 to PM2.5 was determined to make an estimate of relative percentage of coarser particles to fine particles in both feedlot and the dairy representative animal facilities. The maximum mean emission factor determined using AERMOD for PM2.5 and PM10 was found to be 0.53 and 7.09 kg 1000-hd−1 d−1, respectively, for the dairy facility while 8.93 and 33.42 kg 1000-hd−1 d−1, respectively, for the feedlot. A conversion factor and correlation matrix were developed in this study to relate non-FRM sampler data from the handheld AERCET samplers with FRM samplers. Cheaper handheld samplers (AEROCETs) may play a potential role in quick and relatively instant measurement of PM emissions to initiate necessary preventive actions to control PM emission from dairy facility and feedlot sources.
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