The dispersed oxide fillers of different chemical composition were investigated: rutile (TiO2), alumina (Al2O3), calcite (CaO) and hematite (Fe2O3). The mineral composition, surface morphology, particle size and specific surface of the fillers were investigated using modern physicochemical methods. It has been established that the acid-alkaline properties of the active surface centers (ASC) and hydroxyl-hydrate layer (HHL) depend on the chemical and mineral nature of the fillers. It is established that with decreasing acidity of the oxide, the desire for its surface to adsorb water molecules from the air increases. As the alkalinity of the oxide increases, the thickness of both the hydroxyl and hydrate surface layers increases in proportion. It is shown that the acid-alkaline properties of the surface correlate with the acid-alkaline properties of the oxides included in the fillers.
The influence of chemical nature of modifier functional groups on the level of intermolecular interactions in the system "epoxy oligomer ‒ modifier", as well as the structure formation and dynamic viscosity of epoxy oligomer has been studied in detail. Modifying additives in low concentrations contribute to an increase in the degree of structure formation of the epoxy system by increasing the intermolecular interaction between the associates of the epoxydiane oligomer. It was established that the strength of the formed coagulation structures depends both on the compatibility parameter of the modifiers and ED-20, and on their intermolecular interaction energy.
The method of quantum-chemical modeling investigates intermolecular interactions between epoxyamine grid and hydroxides of metals of various chemical nature. It was established that the influence of hydroxide on the structure and spatial conformation of the grid depends on the acid-base properties and increases with increasing alkalinity of the hydroxide. It is shown that for certain an alkaline property of hydroxide, due to strong intermolecular interactions, the spatial conformation of the grid is significantly changed.
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