The kinetics of the oxidative destruction of cobalt phthalocyanine derivatives in aqueous solutions has been investigated in the concentration interval 10−4–10−5 M as a function of the concentration of alkali and the partial pressure of oxygen in the system. The kinetic equation for the initial solution bleaching rate is obtained. A mechanism of cobalt phthalocyanine destruction involving an intermediate Co (II) → Co (III) oxidation step is suggested.

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Accumulation of Cu and Pb by Alisma plantago-aquatica L. plants under laboratory conditions on separate solutions (3 MPC) and changes in the content of heavy metals (HM) when placed on distilled water (control) were studied. The phytoremediation potential of Alisma plantago-aquatica, taken from different stations, is assessed: from conditionally clean habitat located in the middle course of Yagorba river (Cherepovets region) and from conditionally polluted habitat located on the bank of Serovka river within Cherepovets city. It is established that irrespective of what stations are taken plants of Alisma plantago-aquatica, they actively accumulate heavy metals, but plants from conditionally clean habitat accumulate more. More effective in the purification of water from heavy metals is Alisma plantago-aquatica from conditionally clean habitat. Alisma plantago-aquatica specimens from different areas are capable of excretion of Cu and Pb ions, the leaves being the most important in this. Alisma has a good phytoremediation potential and is suitable for inclusion in the composition of bioplato to clean the water of small rivers from Cu and Pb.

Soil biological activity is an integral characteristic reflecting the state of soil fertility, biodiversity, and the activity of soil processes carried out by soil organisms. In Africa, studies of soil biological properties are few compared to the agrochemical research. In this paper, we present an assessment of multiple biochemical and microbiological properties of soil from an agricultural field located in the African tropical savanna. We determined basal respiration, substrate-induced respiration, C of microbial biomass, the potential activity of denitrification, nitrogen fixation activity, and estimated prokaryotic components in the soil microbial complex by quantitative PCR. Basal respiration of soils ranged from 0.77 ± 0.04 to 1.90 ± 0.23 μg C-CO2·g−1·h−1, and substrate-induced respiration ranged from 3.31 ± 0.17 to 7.84 ± 1.04 μg C-CO2·g−1·h−1. The C reserves of microbial biomass averaged 403.7 ± 121.6 μg C·g−1 of soil. The N2O emission from the upper layer on average amounted to 2.79 ng N-N2O·g−1·day−1, and the potential denitrification activity reached 745 ± 98 ng N-N2O·g−1·h−1. The number of copies of bacterial genes varied from (0.19 ± 0.02) × 108 to (3.52 ± 0.8) × 108 copies·g−1, and of archaea—from (0.10 ± 0.01) × 107 to (0.29 ± 0.01) × 107 copies·g−1 of soil. These results were in good agreement with the studies in other seasonally wet tropical regions: the biological activity was relatively low. The difference between biological indicators of the experimental field and the reference profile were insignificant except for nitrogen loss, which was higher in the ploughed field. Biological indicators strongly varied in space; we explained their heterogeneity by non-uniform management practices in the course of agrochemical field experiments in the past. The use of organic fertilisers may cause the release of climatically active gases due to intensive microbial respiration and denitrification, but the intensity of emission would strongly depend on the cultivation and management method.

Die Aktivierungsenergien der Ketonisierung von Essig‐ und Buttersäure bei 350‐400°C an La‐, Pr‐, Nd‐, Sm‐, Eu‐, Gd‐, Tb‐, Dy‐, Ho‐, Er‐, Tm‐, Yb‐ und Lu‐oxid werden bestimmt.