Continents, especially their Archean cores, are underlain by thick thermal boundary layers that have been largely isolated from the convecting mantle over billion-year timescales, far exceeding the life span of oceanic thermal boundary layers. This longevity is promoted by the fact that continents are underlain by highly melt-depleted peridotites, which result in a chemically distinct boundary layer that is intrinsically buoyant and strong (owing to dehydration). This chemical boundary layer counteracts the destabilizing effect of the cold thermal state of continents. The compositions of cratonic peridotites require formation at shallower depths than they currently reside, suggesting that the building blocks of continents formed in oceanic or arc environments and became “continental” after significant thickening or underthrusting. Continents are difficult to destroy, but refertilization and rehydration of continental mantle by the passage of melts can nullify the unique stabilizing composition of continents.

Arc magmas are important building blocks of the continental crust. Because many arc lavas are oxidized, continent formation is thought to be associated with oxidizing conditions. On the basis of copper's (Cu's) affinity for reduced sulfur phases, we tracked the redox state of arc magmas from mantle source to emplacement in the crust. Primary arc and mid-ocean ridge basalts have identical Cu contents, indicating that the redox states of primitive arc magmas are indistinguishable from that of mid-ocean ridge basalts. During magmatic differentiation, the Cu content of most arc magmas decreases markedly because of sulfide segregation. Because a similar depletion in Cu characterizes global continental crust, the formation of sulfide-bearing cumulates under reducing conditions may be a critical step in continent formation.

Abstract-The newly found meteorite Northwest Africa 6234 (NWA 6234) is an olivine (ol)-phyric shergottite that is thought, based on texture and mineralogy, to be paired with Martian shergottite meteorites NWA 2990, 5960, and 6710. We report bulk-rock major-and trace-element abundances (including Li), abundances of highly siderophile elements, Re-Os isotope systematics, oxygen isotope ratios, and the lithium isotope ratio for NWA 6234. NWA 6234 is classified as a Martian shergottite, based on its oxygen isotope ratios, bulk composition, and bulk element abundance ratios, Fe ⁄ Mn, Al ⁄ Ti, and Na ⁄ Al. The Li concentration and d 7 Li value of NWA 6234 are similar to that of basaltic shergottites Zagami and Shergotty. The rare earth element (REE) pattern for NWA 6234 shows a depletion in the light REE (La-Nd) compared with the heavy REE (Sm-Lu), but not as extreme as the known ''depleted'' shergottites. Thus, NWA 6234 is suggested to belong to a new category of shergottite that is geochemically ''intermediate'' in incompatible elements. The only other basaltic or ol-phyric shergottite with a similar ''intermediate'' character is the basaltic shergottite NWA 480. Rhenium-osmium isotope systematics are consistent with this intermediate character, assuming a crystallization age of 180 Ma. We conclude that NWA 6234 represents an intermediate compositional group between enriched and depleted shergottites and offers new insights into the nature of mantle differentiation and mixing among mantle reservoirs in Mars.

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