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This paper is on modeling and measuring fiber-bridging constitutive law of Engineered Cementitious Composites (ECC), a high performance fiber-reinforced cementitious composite featuring high tensile ductility. Fiber-bridging constitutive law plays an important role in the multiple cracking behavior of ECC. Therefore, proper control of fiberbridging behavior through tailoring material microstructure is the key to successfully designing tensile strain-hardening ECC. In this paper, an analytical fiber-bridging model of ECC which connects material constituent parameters and composite properties, built on a previous simplified version, was proposed. To improve accuracy of crack opening prediction, new mechanisms of fiber/matrix interactions, specifically fiber two-way debonding and pull-out, matrix microspalling, and Cook-Gordon effects were included. This revised model was compared with experimental measurement of fiber-bridging behavior and the validity of the model was confirmed. It is expected that this model will greatly improve ECC design technology in terms of steady-state crack width control, key for structural long-term durability, and in terms of composite tensile properties important for structural safety at ultimate limit state.

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Spent Li-ion batteries (LIBs) are highly rich in cobalt and lithium that need to be recovered to reduce shortages of these valuable metals and decrease their potential environmental risks. This study applied bioleaching using Aspergillus niger strains MM1 and SG1 and Acidithiobacillus thiooxidans 80191 for removal of Co and Li from spent LIB under type 1 and type 2 conditions. Moreover, metal recovery was attempted from the fungal leaching solution by sodium sulfide, sodium hydroxide, and sodium oxalate for Co and then for Li using sodium carbonate. The findings of this work show that metal removal in fungal bioleaching under type 2 system was highly comparable or even better than bacterial or acid leaching. A significant quantity of Co (82%) and Li (100%) dissolution was observed in strain MM1; however, metal solubilization was poor in strain 80191 because only 22% Co and 66% Li solubilized. A high amount of Co precipitated potentially as cobalt sulfide (100%), cobalt hydroxide (100%), or cobalt oxalate (88%), whereas Li precipitated as lithium carbonate (73.6%). Finally, results of this study suggest that fungal bioleaching could be an environmentally friendly approach for solubilization and recovery of considerable quantities of metals from spent LIBs.