The CoFe2O4/ZnAl-layered double hydroxide (LDH) composite was successfully developed through a facile co-precipitation method, characterized, and applied as an effective adsorbent for the removal of methyl orange (MO) dye from aqueous solutions. The central composite design (CCD) of the response surface methodology (RSM) was employed to estimate and optimize process variables such as initial MO concentrations, solution pH, adsorbent dosage, and contact time. 98.878% adsorption efficiency was obtained at an initial concentration of 18.747 mg/L of MO, with an adsorbent dosage of 0.048 g, a solution pH of 2.770, and a contact time of 85.890 minutes. Analysis of variance (ANOVA) confirmed the significance of the predicted model (R2 = 0.9844). Kinetic and equilibrium studies indicated that the experimental data for MO adsorption were best described by pseudo-second-order kinetic and Langmuir models. The maximum monolayer adsorption capacity of the CoFe2O4/ZnAl-LDH for MO was 42.3 mg/g.

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Toxic cadmium (Cd) was removed from water using eggshell-based hydroxyapatite (HAp) grafted bentonite (HAp/bentonite) composite through a straightforward chemical synthesis route. The as-prepared adsorbents were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and Brunauer–Emmett–Teller analysis (BET). Optimization of the initial adsorbate concentration, adsorbent dosage, pH, and contact time—all of which affect the adsorption process—was performed using the central composite design (CCD) of the response surface methodology (RSM). 99.3 percent adsorptive removal efficiency was observed at an initial concentration of 61.58 mg/L of Cd (II), with an adsorbent dosage of 1.58 g, a solution pH of 5.88, and a contact time of 49.63 min. The analysis of variance (ANOVA) was performed, and the multiple correlation coefficient (R2) was found to be 0.9915 which confirms the significance of the predicted model. The Langmuir isotherm model best represented the adsorption isotherm data, which also predicted a maximum sorption capacity of 125.47 mg/g. The kinetic data were best described by the pseudo-second order model.