Lattice mismatch with a substrate and difference in coefficient of thermal expansion to the substrate induces stress and deformations in crystalline structure of epitaxially grown layers. In this work, we present results of structural study of gadolinium oxide and erbium oxide grown on silicon (111) substrate applying X-ray diffraction at room temperature and during in-situ heating up to 1273 K. The layers are almost fully relaxed at room temperature. Only minor tetragonal distortion of the crystal lattice was indirectly detected. No thermal induced stress relaxation occurs in the oxide layer during the in-situ heating and cooling procedure though strong tetragonal distortion of the oxide lattice due to thermal expansion difference with silicon. The time-domain thermo-reflectance measurements reveal that thermal conductivity of the rare earth oxides is approximately five times higher than that of silicon dioxide.Rare-earth-metal oxides (REO) grown epitaxially on silicon have attracted much attention primary because of their applications as gate dielectrics for metal-oxide-semiconductor (MOS) devices. 1-4 Additionally, as was demonstrated in some works, 5,6 single crystal rareearth oxides can be considered as a lattice mismatch accommodating buffer for growth of alternative semiconductors on a silicon substrate or for epitaxial semiconductor on insulator (SOI) structures applying from few tens to micrometers thick oxide layers. Stable crystal structure and stoichiometry in temperature range typical for epitaxy and subsequent semiconductor device processing are the main requirements for the buffer dielectric material. According to comprehensive studies of polymorphism of rare-earth oxides by Warshaw et al.,7 Adachi and Imanaka, 8 large ionic radius rare earth sesquioxides (Nd 2 O 3 , Pr 2 O 3 and La 2 O 3 ) have stable hexagonal structure in the range of temperatures typical for epitaxial process. As it was shown in works of other groups that performed epitaxy of silicon on hexagonal praseodymium oxide, 9-11 transferring of the crystallographic stacking sequence from the hexagonal structure of the oxide to cubic structure of semiconductor causes crystal defects in the epitaxially grown semiconductor layer. For this reason, oxides with cubic crystal structure are more preferable for growth of semiconductor on insulator structures. Additionally, lattice constant mismatch between epitaxial dielectric layer and silicon substrate should be small in order to avoid formation of dislocations that propagate up to surface of a grown layer as was demonstrated for Sc 2 O 3 12 and for to cubic bixbyite structure close related calcium fluoride 13 grown on Si(111). From the group of rare-earth oxides, particularly of interest for application as materials for buried dielectric layers for SOI application are the sesquioxides with stable cubic structure and stable oxidation state: Gd 2 O 3 , Er 2 O 3 , Yb 2 O 3 , Lu 2 O 3 . However, their crystal lattice is smaller if compared to that of twice of silicon (from about 0.5% for Gd 2 O...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.