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The CO2 displacement is one of the gasflooding Enhanced Oil Recovery (EOR) methods. The application from volatile oil to black oil is popular mainly because CO2 requires a relatively low miscibility pressure, which is suitable to most reservoir conditions. However, CO2 always contains some impurity, such as CH4, H2S and N2, leading to the change of phase behavior and flooding efficiency. Whether the gasflooding achieves successfully miscible displacement depends on the reservoir pressure and temperature, injected solvent and crude oil compositions. So three different types of oil samples from the real field are selected and mixtures of CH4, H2S and N2 with various CO2 concentrations as the solvent are considered. After a series of experimental data are excellently matched, three nine-pseudocomponent models are generated based on the thermodynamic Equation-of-State (EoS), which are capable of accurately predicting the complicated phase behavior. Three common tools of pressure–temperature (P–T), pressure–composition (P–X) and pseudoternary diagrams are used to display and analyze the alteration of phase behavior and types of displacement mechanism. Simulation results show that H2S is favorable to attain miscibility while CH4 and N2 are adverse, and the former can reduce the Multiple Contact Miscibility (MCM) pressure by the maximum level of 1.675 MPa per 0.1 mol. In addition, the phase envelope of the mixtures CO2/H2S displacing the reservoir oil on the pseudoternary diagram behaves a triangle shape, indicating the condensing-dominated process. While most phase envelopes of CO2/CH4 and CO2/N2 exhibit the trump and bell shapes, revealing the MCM of vaporization.

The re-injection of associated sour gas, with high H2S and CO2 content, into the reservoir is proposed to be an effective development method due to its low investment cost and high oil recovery. The aim of this work is to present the phase behavior and miscible mechanism of crude oil displaced by associated sour gas. Based on the equation of state and the phase equilibrium theory, the phase behavior of crude oil mixed with various gases (associated sour gas, H2S, CO2 and CH4) have been analyzed. Then, the miscibility of associated sour gas was determined by calculating its Minimum Miscible Pressure (MMP) and the effect of sour component fraction on miscibility was evaluated. Moreover, a series of numerical simulations modeling 1D slim-tube were conducted using a compositional simulator to study the miscible mechanism in the displacement of crude oil with associated sour gas. The results show that the injection of H2S can reduce the bubble point pressure of crude oil and therefore is beneficial to prevent the crude oil degassing; nevertheless, the injection of CO2 has little effect on it. The miscible ability of associated sour gas decreases as its sour component fraction decreases. It is observed that the crude oil displaced by associated sour gas and sweet gas both show a combined condensing/vaporizing mechanism, with miscible zone in the middle of transition zone. However, the vaporizing-gas drive mechanism is slightly stronger than the condensing-gas drive mechanism during the displacement by associated sour gas while is significantly stronger during the displacement by sweet gas.

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