Dilute THF-solutions of different fractions of polymers of methyl, ethyl, n-propyl, n-, i-and t-butyl, n-hexyl, 2-ethylhexyl, and lauryl acrylate, prepared by solution polymerization in benzene, were studied by light scattering and viscosity methods. Poly(acry1ic acid) was examined in dioxane. For the different polyacrylic esters the [q]-M,-relations were established and the dependence of the radius of gyration (r:) on the molecular weight was determined. ZUSAMMENFASSUNG:Methyl-, Ethyl-, n-Propyl-, n-, i-und t-Butyl-, n-Hexyl-, 2-Ethylhexyl-und Laurylacrylat wurden in Benzol polymerisiert. Verdiinnte Wsungen in THF einzelner Fraktionen dieser Polymeren wurden durch Lichtstreuungs-und Viskositatsmessungen untersucht. Polyacrylsaure wurde in Dioxan gemessen.Fur die verschiedenen Polyacrylester und Polyacrylsaure wird die Molekulargewichtsabhangigkeit des Staudinger-Index [q] und des Tragheitsradius (r: ) angegeben.
The article contains sections titled: 1. Introduction 2. Properties 2.1. Polymer Solutions and Dispersions 2.1.1. Polymer Solutions 2.1.2. Polymer Dispersions 2.2. Properties of the Polymers 3. Raw Materials 4. Production 4.1. Emulsion Polymerization 4.1.1. Starting Materials 4.1.2. Production Processes 4.2. Solution Polymerization 4.3. Elimination of Residual Monomers 5. Uses 5.1. Paints and Coatings 5.2. Paper Industry 5.3. Adhesives and Sealing Compounds 5.4. Textile Industry 5.5. Leather Industry 5.6. Miscellaneous Uses 6. Toxicology and Environmental Aspects
The article contains sections titled: 1. Introduction 2. Raw Materials 3. Production 3.1. Emulsion Polymerization 3.1.1. Starting Materials 3.1.2. Production Processes 3.2. Solution Polymerization 3.3. Elimination of Residual Monomers 3.4. Toxicology and Environmental Aspects 4. Properties 4.1. Polymer Solutions and Dispersions 4.1.1. Polymer Solutions 4.1.2. Polymer Dispersions 4.2. Properties of the Polymers 5. Uses 5.1. Paints and Coatings 5.2. Paper Industry 5.3. Adhesives and Sealing Compounds 5.4. Textile Industry 5.5. Leather Industry 5.6. Miscellaneous Uses 6. Economic Aspects
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