Dosimetry is a widespread material science field dealing with detection and quantification of ionizing radiation using electronic processes in materials. One of the main aspects that determines the performance of dosimeters is the type of defects the material contains. Crystalline lattice imperfections are formed around impurity ions, which may have a smaller or larger size, or different oxidation states compared to host ions. In this study, we show what effects Cr impurities have on the luminescent properties of alumina. Porous Al 2 O 3 : Cr microceramics synthesized using the sol-gel method showed a higher thermoluminescence response than a single crystal ruby. We have found that Cr 2 O 3 concentration of 0.2 wt% was optimal; it yielded the highest X-ray luminescence and thermostimulated luminescence readout of all studied additive concentrations added to alumina during synthesis. Our results show that Cr doped alumina could potentially be used as a promising new material for dosimetry of ionizing radiation.
The use of stress–strain analysis in structural design or mechanical components is critical for avoiding or investigating structural failures. In the case of complicated designs, mathematical full-field stress modeling produces imprecise predictions. Experimental analysis can be used as a replacement for mathematical modeling, but with the use of currently available strain gauges, it is cumbersome and impossible in the case of moving parts. Mechanoluminescent materials transform mechanical energy into visible light and can be used as a replacement for strain gauges to monitor strain/stress. Three-dimensional printing technology has made major advances in terms of additive manufacturing. In this article, we describe a method to produce an ML 3D print. The fabricated samples are precise and versatile and satisfy the need for easy and non-destructible spatial stress analysis. A 3D printed photopolymer sample with SrAl2O4: Eu, Dy particle addition only to the final layers was tested, and the number of layers was optimized. It was determined that the optimal number of layers for easy detection is in the range of 10 to 20 layers. It opens the possibility for the real-time evaluation of complex uneven forces on complex parts, thus having a good potential for commercialization.
With plasma electrolytic oxidation (PEO), one can easily obtain thick (tens of microns), mechanically resilient and chemically stable oxide coating on aluminum and other valve metal alloys. The study of luminescent PEO coatings is a relatively new subfield of the already well-established coating preparation methods. In recent years, many new luminescence-based approaches have been developed, one of which is the detection of ionizing radiation of carbon-doped PEO alumina coating. This study presents an improved approach by doping the alumina coating with chromium using citric acid as an additive in the electrolyte. Trivalent chromium ions replacing aluminum in the crystalline lattice of the coating exhibit characteristic sharp lines in the luminescence spectrum. The effectiveness of different DC voltages, process times and citric acid concentrations in electrolyte were examined. The use of citric acid in the electrolyte also provides the conditions required for the formation of an energy trap in the bandgap of the material, thus opening up the possibility for the coating to be used as an ionizing radiation detector by measuring its thermoluminescence. Chromium atoms are incorporated in the coating from the Al6082 aluminum alloy itself and are not added in the electrolyte, therefore making the process much more reliable, repeatable, and environmentally friendly.
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