A linear polycation, poly(diallyldimethylammonium chloride), electrostatically interacts with anionic latex particles from a carboxylated butadiene–styrene copolymer in aqueous solution thus forming an interpolyelectrolyte complex. A mutual neutralization of oppositely charged latex and polycation groups occurs at W = latex/polycation = 50 wt/wt ratio. At W = 27, an ultimate polycation adsorption is reached, resulting in the formation of positive polycomplex particles, while at W ˂ 27, two-component systems are formed composed of positive polycomplex particles and free polycation. A film created from the W = 12 formulation shows a high toxicity to Gram-positive and Gram-negative bacteria and yeast. Repeated washing the film leads to partial removal of polycation and a 50% decrease in the activity of the film only towards Gram-negative Pseudomonas aeruginosa. The results indicate the potential for use of the mixed polymer formulations for the fabrication of antimicrobial films and coatings.

Aqueous formulations based on anionic butadiene-styrene microspheres (BSMs) and cationic poly(diallyldimethylammonium chloride) (PDADMAC) with the weight PDADMAC fraction from 0 to 1 were studied as the stabilizers of loose sandy soils. In general, these systems were shown to be represented as the mixtures of microspheres saturated with PDADMAC and unbound polycation. Mechanical testing of BSMs–PDADMAC films evidenced that with increasing weight PDADMAC fraction, a 20-fold growth in elastic modulus, 2-fold growth in strength and 2-fold decrease in ultimate strain of the material were observed. Treatment of the sand with the above formulations resulted in formation of a protective porous polymer-sand surface crust with the strength from 0.8 to 45.0 MPa. “Elasticity–rigidity” balance and water resistance of the crusts were controlled by weight fraction of polycation in the mixed formulation. Stable water-resistant polymer-sand crusts were shown to be prepared using formulations with the weight PDADMAC fraction from 0 to 0.2. The results indicated a great potential of the polymer-colloid formulations for the fabrication of structured sand coatings with controlled properties.