Global overpopulation, industrial expansion, and urbanization have generated massive amounts of wastes. This is considered as a significant worldwide challenge that requires an urgent solution. Additionally, remarkable advances in the field of biomedicine have impacted the entire spectrum of healthcare and medicine. This has paved the way for further refining of the outcomes of biomedical strategies toward early detection and treatment of different diseases. Various nanomaterials (NMs) have been dedicated to different biomedical applications including drug delivery, vaccinations, imaging modalities, and biosensors. However, toxicity is still the main factor restricting their use. NMs recycled from different types of wastes present a pioneering approach to not only avoid hazardous effects on the environment, but to also implement circular economy practices, which are crucial to attain sustainable growth. Moreover, recycled NMs have been utilized as a safe, yet revolutionary alternative with outstanding potential for many biomedical applications. This review focuses on waste recycled NMs, their synthesis, properties, and their potential for multiple biomedical applications with special emphasis on their role in the early detection and control of multiple diseases. Their pivotal therapeutic actions as antimicrobial, anticancer, antioxidant nanodrugs, and vaccines will also be outlined. The ongoing advancements in the design of recycled NMs are expanding their diagnostic and therapeutic roles for diverse biomedical applications in the era of precision medicine.
Graphite powder was introduced into polyvinylidene fluoride via the solution mixing technique. The composites were then subjected to hot compression molding. The effect of dispersion of graphite particles and electrical conductivity of the composites were investigated. Solution mixing enabled homogeneous dispersion of graphite powder within the polyvinylidene fluoride matrix as revealed by transmission electron microscopy. X-ray diffraction and Fourier transform infrared spectroscopy analysis revealed that graphite incorporation induced the α-phase of polyvinylidene fluoride. The DC conductivity results showed that the conductivity increased with an increase in graphite content. Beyond a critical concentration of graphite, percolation threshold, (Φ c = 2.3 vol%) the conductivity increases by five orders of magnitude at 3.9 vol% of graphite powder composite. The electrical conductivity was approximately constant for the composites with the higher graphite loading. Consequently, adding more graphite powder did not significantly alter the electrical conductivity. The correlation between the dispersion of graphite particles and electrical conductivity was discussed. The AC conductivity of composites was investigated in a wide range of frequencies from 50 Hz to 5 MHz and at temperatures ranging from room temperature to 180°C. The conductivity of the composites exhibited strong frequency dependence particularly in the vicinity of the electrical percolation threshold. σAC obeyed the power law of the form: [Formula: see text], where ω is the angular frequency and s and A the characteristic parameters. The values of the exponent ( s) were found to decrease with increasing temperature which is consistent with the correlated barrier-hopping model.
The growth of the textile industry results in a massive accumulation of dyes on water. This enormous rise in pigments is the primary source of water pollution, affecting the aquatic lives and our ecosystem balance. This study aims to notify the fabrication of neodymium incorporated copper oxide (Nd2O3 doped CuO) nanoparticles by combustion method for effective degradation of dye, methylene blue (MB). X-ray diffraction (XRD), Field emission Scanning electron microscopy (FESEM), Zeta potential have been applied for characterization. Photocatalyst validity has been evaluated for methylene blue degradation (MB). Test conditions such as time of contact, H2O2, pH, and photo-Fenton have been modified to identify optimal degradation conditions. Noticeably, 7.5% Nd2O3 doped CuO nanoparticle demonstrated the highest photocatalytic efficiency, up to 90.8% in 80 min, with a 0.0227 min−1 degradation rate. However, the photocatalytic efficiency at pH 10 becomes 99% with a rate constant of 0.082 min−1. Cyclic experiments showed the Nd2O3 doped CuO nanoparticle’s stability over repeated use. Scavenge hydroxyl radical species responsible for degradation using 7.5% Nd2O3 doped CuO nanoparticles have been investigated under visible irradiation.
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