Solid state UV emitters have many advantages over conventional UV sources. The (Al,In,Ga)N material system is best suited to produce LEDs and laser diodes from 400 nm down to 210 nm—due to its large and tuneable direct band gap, n- and p-doping capability up to the largest bandgap material AlN and a growth and fabrication technology compatible with the current visible InGaN-based LED production. However AlGaN based UV-emitters still suffer from numerous challenges compared to their visible counterparts that become most obvious by consideration of their light output power, operation voltage and long term stability. Most of these challenges are related to the large bandgap of the materials. However, the development since the first realization of UV electroluminescence in the 1970s shows that an improvement in understanding and technology allows the performance of UV emitters to be pushed far beyond the current state. One example is the very recent realization of edge emitting laser diodes emitting in the UVC at 271.8 nm and in the UVB spectral range at 298 nm. This roadmap summarizes the current state of the art for the most important aspects of UV emitters, their challenges and provides an outlook for future developments.
Non-and semipolar GaN-based optoelectronic device structures have attracted much attention in recent years. Best results have been obtained on small bulk substrates cut from thick c-plane epi-wafers. However, owing to the limited size of such substrates, it is very attractive to study hetero-epitaxial approaches on foreign substrates. In this paper, we review the current state of such studies which eventually lead to large area non-or semipolar nitride structures. The simplest approach is to use planar sapphire or SiC wafers of non-c-plane orientations on which potentially less polar GaN can be grown. However, typically huge dislocation and in particular stacking fault densities evolve. More sophisticated approaches make use of the good GaN growth performance in the c-direction, eventually leading anyway to large area non-or semipolar structures. Several such approaches are discussed in this paper.
By using picosecond time-resolved photoluminescence we have measured the lifetime of excess charge carriers in GaN epitaxial layers grown on sapphire at temperatures up to 300 K. The decay time turns out to be dominated by trapping processes at low excitation levels. The radiative lifetime derived from our data is dominated by free excitons at temperatures below 150 K, but also clearly shows the gradual thermal dissociation of excitons at higher temperatures. From our data, we are able to determine the free exciton binding energy and the free carrier radiative recombination coefficient. By combining these data with optical absorption data, we find the interband momentum matrix element and an estimate for the hole effective mass, which is much larger than previously thought.
Photoluminescence (PL) spectroscopy with subwavelength lateral resolution has been employed to probe individual localization centers in a thin InGaN/GaN quantum well. Spectrally narrow emission lines with a linewidth as small as 0.8 meV can be resolved, originating from the recombination of an electron-hole pair occupying a single localized state. Surprisingly, the individual emission lines show a pronounced blueshift when raising the temperature, while virtually no energy shift occurs for increasing excitation density. These findings are in remarkable contrast to the behavior usually found in macro-PL measurements and give a fundamental new insight into the recombination process in semiconductor nanostructures in the presence of localization and strong internal electric fields. We find clear indications for a biexciton state with a negative binding energy of about -5+/-0.7 meV.
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