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New golden, yellow-colored cerium chemical conversion coatings on aluminum alloy 2024-T3 (AA2024-T3 [UNS A92024]) surface at room temperature were obtained by immersing the alloy into a cerium solution containing zinc chloride (ZnCl2) and hydrogen peroxide (H2O2). Electrochemical methods and immersion tests were used to study the dynamics of the coatings formation and their corrosion resistance in 3.5% sodium chloride (NaCl) solution. The morphologies of the coatings were recorded by scanning electronic microscopy (SEM). Energy-dispersive x-ray (EDX) analysis and x-ray photoelectron spectroscopy (XPS) were used to analyze the chemical composition and the oxidation state of the elements in the coatings. Polarization experiments and immersion tests in 3.5% NaCl solution showed that the sensitivity to pitting corrosion for the conversion-coated AA2024-T3 was greatly lower than that of the untreated specimens, and the corrosion resistance improved markedly. SEM photographs showed that the coatings consisted of a lot of spherical particles. EDX and XPS experimental results showed that the coatings were made up of oxygen, cerium, and aluminum, and the spherical particles contained higher contents of cerium and oxygen than the other sites. Cerium was mainly in the form of Ce4+. The mechanisms of conversion coatings formation and improvement on corrosion resistance also are discussed.

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Physicochemical protection of soil carbon provided by soil aggregates is critical to carbon (C) sequestration in terrestrial ecosystems. However, the stability of soil organic matter (SOM) in terrestrial ecosystems in response to atmospheric nitrogen (N) deposition is unclear. In this study, N was added to a forest soil dominated by deciduous trees on Changbai Mountain, China, at three different rates (0, 25 and 50 kg N ha−1 year−1) from 2007 to 2012. Its effect on C content and stabilization was evaluated by soil fractionation and stable isotope (δ13C) analyses. The results showed that large macroaggregates (2–8 mm) decreased and small macroaggregates (0.25–2 mm) increased with increasing rates of N addition, whereas soil C content remained unchanged. Irrespective of the N treatments, the C content of soil organic matter (SOM) fractions differed significantly between large and small macroaggregates, which suggests that the size of aggregate classes regulates C content in the SOM fractions. A slight increase in the C content of microaggregates within macroaggregates (Mm) and that of silt and clay fractions was recorded with the addition of N at 50 kg N ha−1 year−1. This increase also occurred in the silt and clay fraction within microaggregates (Intra‐SC). Unprotected C (comprising the free light fraction (Free‐LF) and coarse particulate organic matter (CPOM)) accounted for 18.9% only of the total C and decreased in response to the addition of N. The δ13C signature and C/N ratios obtained for SOM fractions showed that newly formed C was transferred from POM to Intra‐SC. Overall, our results suggested that long‐term addition of N might promote stabilization of C by increasing small macro‐ and micro‐aggregation within macroaggregates in temperate forest soil. Highlights Investigated stability of soil organic matter in response to long‐term N addition in a deciduous forest. Physicochemical protection of soil organic matter by aggregates changed after N addition. Soil organic carbon in microaggregates within macroaggregates increased with N addition. Long‐term N addition might promote C stabilization in temperate forest soil.