Various mechanisms of electrical generation of spin polarization in nonmagnetic materials have been a subject of broad interest for their underlying physics and device potential in spintronics. One such scheme is chirality-induced spin selectivity (CISS), with which structural chirality leads to different electric conductivities for electrons of opposite spins. The resulting effect of spin filtering has been reported for a number of chiral molecules assembled on different surfaces. However, the microscopic origin and transport mechanisms remain controversial. In particular, the fundamental Onsager relation was argued to preclude linear-response detection of CISS by a ferromagnet. Here, we report definitive observation of CISS-induced magnetoconductance in vertical heterojunctions of (Ga,Mn)As/AHPA-L molecules/Au, directly verifying spin filtering by the AHPA-L molecules via spin detection by the (Ga,Mn)As. The pronounced and robust magnetoconductance signals resulting from the use of a magnetic semiconductor enable a rigorous examination of its bias dependence, which shows both linear-and nonlinear-response components. The definitive identification of the linear-response CISS-induced two-terminal spin-valve effect places an important constraint for a viable theory of CISS and its device manifestations. The results present a promising route to spin injection and detection in semiconductors without using any magnetic material.

Thermoelectric conversion of low temperature, delocalized, and abundant thermal sources is crucial for the development of the Internet of Things (IoT) and/or a carbon-free society. Thermocells are of great interest in thermoelectric conversion of low-temperature heat due to the low cost and flexibility of components. However, significant improvement of the conversion efficiency is required for the practical use of the cells. Here, we report thermo-electrochemical cells driven by volume phase transition (VPT) of hydrogel nanoparticles (NPs). Entropically driven VPT of poly(N-isopropylacrylamide) NPs containing carboxylic acids and amines generates a pH gradient of up to 0.049 and −0.053 pH K −1 , respectively, around physiological temperature. The pH gradient triggers the proton-coupled electron transfer (PCET) reactions of quinhydrone on the electrodes, resulting in the highly efficient thermoelectric conversion with a Seebeck coefficient (S e ) of −6.7 and +6.1 mV K −1 . Thermocells driven by phase transition of hydrogels provide a nontoxic, flexible, and inexpensive charger that harvests carbon-free energy from abundant energy sources such as solar, body and waste heat.

Low Earth orbit (LEO) satellites located at altitudes of 500 km~1500 km can carry much stronger signals and move faster than medium Earth orbit (MEO) satellites at about a 20,000 km altitude. Taking advantage of these features, LEO satellites promise to make contributions to navigation and positioning where global navigation satellite system (GNSS) signals are blocked as well as the rapid convergence of precise point positioning (PPP). In this paper, LEO-based optimal global navigation and augmentation constellations are designed by a non-dominated sorting genetic algorithm III (NSGA-III) and genetic algorithm (GA), respectively. Additionally, a LEO augmentation constellation with GNSS satellites included is designed using the NSGA-III. For global navigation constellations, the results demonstrate that the optimal constellations with a near-polar Walker configuration need 264, 240, 210, 210, 200, 190 and 180 satellites with altitudes of 900, 1000, 1100, 1200, 1300, 1400 and 1500 km, respectively. For global augmentation constellations at an altitude of 900 km, for instance, 72, 91, and 108 satellites are required in order to achieve a global average of four, five and six visible satellites for an elevation angle above 7 degrees with one Walker constellation. To achieve a more even coverage, a hybrid constellation with two Walker constellations is also presented. On this basis, the GDOPs (geometric dilution of precision) of the GNSS with and without an LEO constellation are compared. In addition, we prove that the computation efficiency of the constellation design can be considerably improved by using master–slave parallel computing.

Abstract:Ground-based GNSS-R (global navigation satellite system reflectometry) can provide the absolute vertical distance from a GNSS antenna to the reflective surface of the ocean in a common height reference frame, given that vertical crustal motion at a GNSS station can be determined using direct GNSS signals. This technique offers the advantage of enabling ground-based sea level measurements to be more accurately determined compared with traditional tide gauges. Sea level changes can be retrieved from multipath effects on GNSS, which is caused by interference of the GNSS L-band microwave signals (directly from satellites) with reflections from the environment that occur before reaching the antenna. Most of the GNSS observation types, such as pseudo-range, carrier-phase and signal-to-noise ratio (SNR), suffer from this multipath effect. In this paper, sea level altimetry determinations are presented for the first time based on geometry-free linear combinations of the carrier phase at low elevation angles from a fixed global positioning system (GPS) station. The precision of the altimetry solutions are similar to those derived from GNSS SNR data. There are different types of observation and reflector height retrieval methods used in the data processing, and to analyze the performance of the different methods, five sea level determination strategies are adopted. The solutions from the five strategies are compared with tide gauge measurements near the GPS station, and the results show that sea level changes determined from GPS SNR and carrier phase combinations for the five strategies show good agreement (correlation coefficient of 0.97-0.98 and root-mean-square error values of <0.2 m).