Developing novel techniques to convert lignin into sustainable chemicals and functional materials is a critical route toward the high-value utilization of lignocellulosic biomass. Lignin-derived carbon materials hold great promise for applications in energy and chemical engineering, catalysis and environmental remediation. In this review, the state-of-art sciences and technologies for controllable synthesis of lignin-derived carbon materials are summarized, pore structure engineering, crystalline engineering, and morphology controlling methodologies are thoroughly outlined and critically discussed. Green chemical engineering with cost-effectiveness and precise carbonization tuning microstructure are future research trends of lignin-derived carbon materials. Future research directions that could be employed to advance lignin-derived carbon materials toward commercial applications are then proposed.
In this work, lignin-decorated
ZnO composite was prepared via an
in situ synthesis method using industrial alkali lignin (AL). First,
the AL was modified by quaternization to prepare quaternized alkali
lignin (QAL). The microstructure and optical properties of the QAL/ZnO
composite were characterized by scanning electron microscopy (SEM),
transmission electron microscopy (TEM), X-ray diffraction (XRD), and
UV–vis and photoluminescence (PL) spectroscopy. These results
showed that the prepared QAL/ZnO composite possessed a flowerlike
structure and showed excellent synergistic UV-absorbent properties.
Interestingly, the anti-UV performance and mechanical properties of
polyurethane (PU) were significantly improved when it was blended
with the resulting QAL/ZnO. In comparison with pure PU film, the UV
transmittance of the PU film was rapidly reduced. Furthermore, the
tensile strength and elongation at break of PU film blended with QAL/ZnO
were significantly improved, which was due to good compatibility between
QAL/ZnO and PU matrix. Results of this work provide a significant
and practical approach for the high value-added utilization of lignin
as a functional material.
Industrial waste lignosulfonate is used to prepare high valued carbon materials. • LS/ZnC 2 O 4 composite is fabricated in ethanol/water solution without any toxic material. • PLC is prepared by Gas-exfoliation and In-situ templating carbonization technique. • PLC with rational pore distribution, large surface area, and excellent conductivity. • PLC supercapacitor shows great electrochemical performances in energy storage.
In this work, lignin/zinc oxide nanocomposites with excellent UV-absorbent performance were prepared through a novel hydrothermal method using industrial alkali lignin (AL) as raw materials. AL was first modified by quaternization to synthesize quaternized alkali lignin (QAL). The QAL/ZnO nanocomposites with different lignin contents were then prepared via a facile one-step hydrothermal method using QAL and zinc nitrate hexahydrate and hexamethylenetetramine in aqueous solution. The prepared nanocomposite possessed an average diameter of ∼100 nm and showed excellent synergistic UV-absorbent performance. The particle morphology and hybrid structure were carefully characterized by SEM, TEM, XRD, FT-IR, XPS, UV−vis, and TG analyses. Interestingly, it was found that the UV transmittance of polyurethane (PU) film was significantly reduced and the mechanical properties of the PU were significantly enhanced when blended with the prepared QAL/ZnO nanocomposite. The results of this work were of practical importance for high value-added application of industrial lignin in the field of functional materials.
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