The dye-doped polymer is commonly used in the field of optoelectronics, given its effectiveness in optimising the device’s performance. This study is devoted to the synthesis and characterisation of Anchusa-Italica-doped Pentacene thin-film. Scanning electronic microscopy structural analysis, Fourier transform spectroscopy, and UV-visible transmittance spectra with a range of 300-900 nm were also carried out. The fundamental optical properties such as the absorption coefficient, optical energy gap, absorption and refractive indices were calculated based on the methods already used in the literature as Tauc’s relationship. The morphology of the samples indicated that dye structure was affected in the doped pentacene. The Fourier transform infrared technique (FT-IR) resulting spectrum of the doped samples also showed a significant absorption peak corresponding to C-H as an index of impurities. The calculated band-gap energy of the impurity sample was reduced and was the lowest compared to both the pure dye and polymer samples. The optical absorption and transmittance spectra revealed that it was positioned in the desirable ranges for optoelectronic applications. An anomaly in the absorption index was also observed through excitation of the resonance mode with transparent indication. This effect was deduced from the calculation of the refractive index. The results presented in this paper significantly contribute to the developments in the field of optoelectronic devices based on dye/polymer organic materials.
In this study, thin films of PMMA Poly (methyl methacrylate)- Polyvinylidene fluoride(PMMA-PVDF), PMMA polymer and soluble PVDF polymer were prepared at (5%)Toluene and polymeric blends in 1:1 volume ratio of polymers and in different proportions of polymers. The studied films were prepared by the Spin coating method, and the optical parameters of the thin films were measured within a range (300-900)nm and the thickness of the films were constant (223 nm). Absorbance (A), linear absorption coefficient (α), refractive index (n), extinction coefficient (K), real and imaginary dielectric constant (∈r, ∈i), and optical energy gap Eg were studied, as the best edge of optical absorption was 5% PVDF, And electronic transmission between levels was direct transmission.
On the earth's surface, the sun is a source of light energy. Electrical energy was produced when solar energy was converted into free energy charged within the particles of some materials. Organic solar cells (OSCs) have gotten a lot of attention because of their advantages like low cost and flexibility. It is semi-transparent, non-toxic, and ideal for mass production. OSCs with high-performance active layer materials, electrodes, and interlayers have made significant progress, as have novel device architectures. In particular, active layer material innovation allows for the possibility of achieving high performance in OSC by using absorbent materials; polymers are commonly used as absorbent layers to induce light absorption efficiency and device performance.
This work is devoted to the influence of magnetized water on dye extracted from Anchusa Italica plant and doped pentacene thin films. The findings resulted in optoelectronic behavior, showing that using magnetized water in the extraction process gives rise to distinct and superior characteristics as compared to using regular water. The Fourier-transform infrared method was used to analyze the structural properties of an Anchusa Italica-doped pentacene thin film. A comparative study on two samples was carried out: the first sample was affected by a static magnetic field and the other one was not. Optical properties including the absorption spectra absorption coefficient, optical energy gap, conventional and refractive factors were investigated by applying ultraviolet-visible spectroscopy ranging from 300 to 900 nm. The estimated band gap edge of the dye/doped pentacene affected with magnetization was reduced from 2.61 to 1.76 eV and converted into the recommended direct band gap to contribute to optical systems. The absorption spectra of the sample with magnetization effect appears to be more efficient than the one extracted using regular water. The power transmission coefficients (indirect to direct) were also affected because of the magnetic extraction procedure. The complex refractive index was used to study the magnetization effect on the resonance mode and transparent indicator. The absorption index was enhanced to 570 nm in the spectrum, whereas there was also a low attenuation coefficient. This is the first time that magnetized sol has been used in dye extraction processes.
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