Electrospinning technology, which was previously known as a scientific interdisciplinary research approach, is now ready to move towards a practice-based interdisciplinary approach in a variety of fields, progressively. Electrospun nanofiber-applied products are made directly from a nonwoven fabric-based membranes prepared from polymeric liquids involving the application of sufficiently high voltages during electrospinning. Today, electrospun nanofiber-based materials are of remarkable interest across multiple fields of applications, such as in electronics, sensors, functional garments, sound proofing, filters, wound dressing and scaffolds. This article presents such a review for summarizing the current progress on the manufacturing scalability of electrospun nanofibers and the commercialization of electrospun nanofiber products by dedicated companies globally. Despite the clear potential and limitless possibilities for electrospun nanofiber applications, the uptake of electrospinning by the industry is still limited due to the challenges in the manufacturing and turning of electrospun nanofibers into physical products. The recent developments in the field of electrospinning, such as the prominent nonwoven technology, personal views and the potential path forward for the growth of commercially applied products based on electrospun nanofibers, are also highlighted.
Electrospun polymer nanofibers with high surface area to volume ratio and tunable characteristic are formed through the application of strong electrostatic field. Electrospinning has been identified as a straight forward and viable technique to produce nanofibers from polymer solution as their initial precursor. These nanofiber materials have attracted attention of researchers due to their enhanced and exceptional nanostructural characteristics. Electrospun polyaniline (PANI) based nanofiber is one of the important new materials for the rapidly growing technology development such as nanofiber based sensor devices, conductive tissue engineering scaffold materials, supercapacitors, and flexible solar cells applications. PANI however is relatively hard to process compared to that of other conventional polymers and plastics. The processing of PANI is daunting, mainly due to its rigid backbone which is related to its high level of conjugation. The challenges faced in the electrospinning processing of neat PANI have alternatively led to the development of the electrospun PANI based composites and blends. A review on the research activities of the electrospinning processing of the PANI based nanofibers, the potential prospect in various fields, and their future direction are presented.
The development of antimicrobial packaging has been growing rapidly due to an increase in awareness and demands for sustainable active packaging that could preserve the quality and prolong the shelf life of foods and products. The addition of highly efficient antibacterial nanoparticles, antifungals, and antioxidants to biodegradable and environmentally friendly green polymers has become a significant advancement trend for the packaging evolution. Impregnation of antimicrobial agents into the packaging film is essential for impeding or destroying the pathogenic microorganisms causing food illness and deterioration. Higher safety and quality as well as an extended shelf life of sustainable active packaging desired by the industry are further enhanced by applying the different types of antimicrobial packaging systems. Antimicrobial packaging not only can offer a wide range of advantages, but also preserves the environment through usage of renewable and biodegradable polymers instead of common synthetic polymers, thus reducing plastic pollution generated by humankind. This review intended to provide a summary of current trends and applications of antimicrobial, biodegradable films in the packaging industry as well as the innovation of nanotechnology to increase efficiency of novel, bio-based packaging systems.
Titanium dioxide (TiO2) is an antimicrobial agent which is considered of potential value in inhibiting the growth of multiple bacteria. Klebsiella pneumonia and Haemophilus influenza are two of the most common respiratory infection pathogens, and are the most. Klebsiella pneumonia causes fatal meningitis, while Haemophilus influenza causes mortality even in younger patients. Both are associated with bacteremia and mortality. The purpose of this study was to test a new antibacterial material, namely nanotitania extract combined with 0.03% silver that was developed at Universiti Malaysia Sabah (UMS) and tested against K. pneumonia and H. influenza. The nanoparticles were synthesized through a modified hydrothermal process, combined with molten salt and proven to have excellent crystallinity, with the band-gap energy falling in the visible light spectrum. The nanoparticle extract was tested using a macro-dilutional method, which involved combining it with 0.03% silver solution during the process of nanoparticle synthesis and then introducing it to the bacteria. A positive control containing the bacteria minus the nanoparticles extract was also prepared. 25 mg/mL, 12.5 mg/mL, and 6.25 mg/mL concentrations of the samples were produced using the macro dilution method. After adding the bacteria to multiple concentrations of nanoparticle extract, the suspensions were incubated for 24 h at a temperature of 37 °C. The suspensions were then spread on Mueller-Hinton agar (K. pneumonia) and chocolate blood agar (H. influenza), where the growth of bacteria was observed after 24 h. Nanoparticle extract in combination with silver at 0.03% was proven to have potential as an antimicrobial agent as it was able to inhibit H. influenza at all concentrations. Furthermore, it was also shown to be capable of inhibiting K. pneumonia at concentrations of 25 mg/mL and 50 mg/mL. In conclusion, the nanoparticle extract, when tested using a macro-dilutional method, displayed antimicrobial properties which were proven effective against the growth of both K. pneumonia and H. influenza.
There are a relatively large number of studies on surfactants facilitates the dispersion of multi-walled carbon nanotubes (MWCNTs), however reports for both orientation and size aggregation of surfactants on MWCNTs are scarcely described. In this study, we demonstrate the visualization of the surfactants aggregates onto MWCNTs using atomic force microscopic (AFM) and field emission electron scanning microscopy (FESEM) to provide information on the orientation and the grains size of surfactants-MWCNTs aggregates. MWCNTs treated with surfactants of different charges, namely sodium dodecyl sulphate (SDS), the anionic, cetyltrimethyl ammonium bromide (CTAB), the cationic and polysorbate 80 (Tween-80), the non-ionic, displayed substantial pattern of surfactant-MWCNTs surface contours. Raman spectroscopy analysis has been presented in order to report the characteristic of defective MWCNTs graphitize structure upon non-covalent adsorption of respective surfactants.
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