Here we report a giant, completely reversible magneto-electric coupling of 100 nm polycrystalline Co layer in contact with ZnO nanorods. When the sample is under an applied bias of ±2 V, the Co magnetic coercivity is reduced by a factor 5 from the un-poled case, with additionally a reduction of total magnetic moment in Co. Taking into account the chemical properties of ZnO nanorods measured by X-rays absorption near edge spectroscopy under bias, we conclude that these macroscopic effects on the magnetic response of the Co layer are due to the microstructure and the strong strain-driven magneto-electric coupling induced by the ZnO nanorods, whose nanostructuration maximizes the piezoelectric response under bias.
The evolution of the aggregation of condensed matter from single atoms to three-dimensional structures represents an important topic in nanoscience, since it contains essential information to achieve tailor-made growth of...
The possibility of
depositing precisely mass-selected Ag clusters
(Ag
1
, Ag
3
, and Ag
7
) on Ru(0001) was
instrumental in determining the importance of the in-plane coordination
number (CN) and allowed us to establish a linear dependence of the
Ag 3d
5/2
core-level shift on CN. The fast cluster surface
diffusion at room temperature, caused by the low interaction between
silver and ruthenium, leads to the formation of islands with a low
degree of ordering, as evidenced by the high density of low-coordinated
atomic configurations, in particular CN = 4 and 5. On the contrary,
islands formed upon Ag
7
deposition show a higher density
of atoms with CN = 6, thus indicating the formation of islands with
a close-packed atomic arrangement. This combined experimental and
theoretical approach, when applied to clusters of different elements,
offers the perspective to reveal nonequivalent local configurations
in two-dimensional (2D) materials grown using different building blocks,
with potential implications in understanding electronic and reactivity
properties at the atomic level.
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