Light-emitting diode (LED) efficiency has attracted considerable interest because of the extended use of solid-state lighting. Owing to lack of direct measurement, identification of the reasons for efficiency droop has been restricted. A direct measurement technique is developed in this work for characterization of biaxial stress in GaN-based blue LEDs under electrical injection. The Raman shift of the GaN E2 mode evidently decreases by 4.4 cm−1 as the driving current on GaN-based LEDs increases to 700 mA. Biaxial compressive stress is released initially and biaxial tensile stress builds up as the current increases with respect to the value of stress-free GaN. First-principles calculations reveal that electron accumulation is responsible for the stress variation in InxGa1−xN/GaN quantum wells, and then reduces the transition probability among quantum levels. This behavior is consistent with the measured current-dependent external quantum efficiency. The rule of biaxial stress-dependent efficiency is further validated by controlling the biaxial stress of GaN-based LEDs with different sapphire substrate thicknesses. This work provides a method for direct observation of the biaxial stress effect on efficiency droop in LEDs under electrical injection.
To understand characteristics of on-line oxidation-reduction potential (ORP) in a subsurface wastewater infiltration system (SWIS) under different intermittent influent conditions, ORP among five matrix depths at wet-dry ratios (Rwds) of 2:1, 1:1 and 1:2 with a hydraulic load of 0.10 m3·(m2·d)−1 were monitored. Results showed that the optimal Rwd for the SWIS was 1:1. In that case, ORP at 40 and 65 cm depths changed significantly, by 529 mV and 261 mV, respectively, from the inflow period to the dry period, which was conducive to the recovery of the oxidation environment. It was concluded that ORP varied nonlinearly in strongly aerobic and hypoxic environment. Wastewater was fed into the SWIS at 80 cm and dissolved oxygen diffused at the initial period of one cycle. As a consequence, ORP at 65 cm increased with water content increasing. However, ORP at 40 and 95 cm displayed inverse trends. Moreover, results showed that ORP decreased with Fe2+ and Mn2+ increasing under aerobic conditions (p < 0.05) because Fe2+ and Mn2+ moved with wastewater flow. Effluent met reuse requirements and no clogging was found in the SWIS during the operation.
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