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Hollow lanthanide-doped compounds are some of the most popular materials for high-performance luminescent devices. However, it is challenging to find an approach that can fabricate large-scale and well-crystallized lanthanide-doped hollow structures and that is facile, efficient and of low cost. In this study, YBO3: Eu3+/Tb3+ hollow microspheres were fabricated by using a novel multi-step transformation synthetic route for the first time with polystyrene spheres as the template, followed by the combination of a facile homogeneous precipitation method, an ion-exchange process and a calcination process. The results show that the as-obtained YBO3: Eu3+/Tb3+ hollow spheres have a uniform morphology with an average diameter of 1.65 µm and shell thickness of about 160 nm. When used as luminescent materials, the emission colours of YBO3: Eu3+/Tb3+ samples can be tuned from red, through orange, yellow and green-yellow, to green by simply adjusting the relative doping concentrations of the activator ions under the excitation of ultraviolet light, which might have potential applications in fields such as light display systems and optoelectronic devices.

Monodisperse hollow microspherical YPO 4 :Ln 3+ (Ln 3+ = Eu 3+ /Tb 3+) with diameters of around 2.5 µm have been successfully synthesised by combining a convenient homogeneous precipitation method, an ion exchange method, and a calcination process for the first time. X-ray diffraction, Fourier transform infrared, thermogravimetric analysis, scanning electron microscopy, transmission electron microscopy, and photoluminescence spectra were used to characterise the samples. Upon ultraviolet excitation, Eu 3+-and Tb 3+-doped microspherical YPO 4 showed typical red and green emission, respectively, which provide potential applications in bioanalysis, future colour displays, lightemitting devices, and so on.

A hard template strategy is developed to fabricate the LuBO3: Eu3+/Tb3+ hollow microspheres using a novel multi-step transformation synthetic route for the first time with polystyrene (PS) spheres as the template, followed by the combination of a facile homogeneous precipitation method, an ion-exchange process, and a calcination process. The results show that the as-obtained LuBO3: Eu3+/Tb3+ hollow spheres have a uniform morphology with an average diameter of 1.8 μm and shell thickness of about 80 nm. When used as luminescent materials, the emission colors of LuBO3: Eu3+/Tb3+ samples can be tuned from red, through orange, yellow and green-yellow, to green by simply adjusting the relative doping concentrations of the activator ions under the excitation of ultraviolet (UV) light, which might have potential applications in the field such as light display systems and optoelectronic devices.