To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation (Es3l), samples with different features were selected and analyzed using N2 adsorption, high‐pressure mercury injection capillary pressure (MICP), nuclear magnetic resonance (NMR), high‐speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil‐wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately; thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro‐cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large‐scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.
A set of nodular limestones was developed in the first member of the Middle Permian Maokou Formation (denoted as the Mao‐1 member) in the south‐eastern Sichuan Basin, south‐west China. Borehole coring has shown excellent signals of oil and gas from the Mao‐1 member carbonates, and many drilling wells have obtained industrial‐level gas flow. To assess the natural gas exploration potential of the Mao‐1 member in this area, sedimentary characteristics of drilling cores are described, and the formation mechanism of natural gas reservoir and its key controlling factors are also evaluated using data obtained from field geological survey, core observation, and laboratory experimental analysis. On this basis, the process of natural gas accumulation and evolution is examined. The results show that the Mao‐1 member nodular limestone comprises abundant marls and packstone to wackestone, and they were deposited in a lower part of the carbonate ramp setting. The marls exhibit rather high organic‐matter abundance and hydrocarbon generation capacity. Natural gas is mostly enriched in the marls developed talc diagenetic shrinkage pores and a certain number of organic‐matter pores, and their reservoir properties are much better than that of packstone‐wackestone. The natural gas in the Mao‐1 member is mainly self‐generated oil pyrolysis gas. The gas reservoir is characterized by the co‐existence of source rocks and reservoir, a lithology‐controlled reservoir, and a structure‐fracture‐controlled enrichment mechanism. Organic‐matter‐rich marl constitutes the material basis for natural gas accumulation. Talc diagenetic shrinkage pores provide storage space for natural gas. Preservation conditions are the key to natural gas accumulation, and natural fractures are beneficial to high gas production. The gas reservoir is characterized by early intraformational enrichment and late interformational adjustment. The finding of the nodular limestone gas reservoir of the Mao‐1 member provides new insights into unconventional gas exploration in the Sichuan Basin, and shows great potential for increasing natural gas reserves and production in China.
A thermal barrier coating forms a high temperature resistant metal by the spraying of ceramics or other materials. Thermal barrier coatings are mainly used in the aviation field because they can significantly improve the thermal resistance of the aircraft engine turbine blades, combustion chamber and the other hot parts. In this paper, a thermal barrier coating model of the combustion chamber is established by using the finite element method. The stress field and displacement field of thermal barrier coatings under different thicknesses of the thermally grown oxide layer and thermal barrier coating layer, and the maximum operating temperature were studied. The results show that stress and deformation under the three thermal cycles increase with the increase in operating temperature and the thickness of thermally grown oxide (TGO) and thermal barrier coat (TBC), except for the case of TGO thickness of 2 μm.
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