Magnetorheological (MR) fluids are capable of manifesting a rheological behaviour change by means of a magnetic field application and can be employed in many complex systems in many technical fields. One successful example is their use in the development of dampers: magnetorheological dampers (MRDs) are widespread in vibration control systems, as well as civil engineering applications (i.e., earthquake or seismic protection), impact absorption and vibration isolation technology in industrial engineering, and advanced prosthetics in biomedical fields. In the past, many studies have been conducted on MRDs modeling and characterization, but they have usually been focused more on the theoretical models than on the experimental issues. In this work, an overview of both of them is proposed. In particular, after an introduction to the physics of the magnetorheological effect, a short review of the main mathematical models of MRDs is proposed. Finally, in the second part of this study an overview of the main issues that occur in MRDs experimental characterization is reported and discussed.
We introduce an architecture based on deep hierarchical decompositions to learn effective representations of large graphs. Our framework extends classic R-decompositions used in kernel methods, enabling nested part-of-part relations. Unlike recursive neural networks, which unroll a template on input graphs directly, we unroll a neural network template over the decomposition hierarchy, allowing us to deal with the high degree variability that typically characterize social network graphs. Deep hierarchical decompositions are also amenable to domain compression, a technique that reduces both space and time complexity by exploiting symmetries. We show empirically that our approach is competitive with current state-of-the-art graph classification methods, particularly when dealing with social network datasets.
The number of studies on microgrippers has increased consistently in the past decade, among them the numeric simulations and material characterization are quite common, while the metrological issues related to their performance testing are not well investigated yet. To add some contribution in this field, an image analysis-based method for microgrippers displacement measurement and testing is proposed here: images of a microgripper prototype supplied with different voltages are acquired by an optical system (i.e., a 3D optical profilometer) and processed through in-house software. With the aim to assess the quality of the results a systematic approach is proposed for determining and quantifying the main error sources and applied to the uncertainty estimation in angular displacement measurements of the microgripper comb-drives. A preliminary uncertainty evaluation of the in-house software is provided by a Monte Carlo Simulation and its contribution added to that of the other error sources, giving an estimation of the relative uncertainty up to 3.6% at 95% confidence level for voltages from 10 V to 28 V. Moreover, the measurements on the prototype device highlighted a stable behavior in the voltage range from 0 V to 28 V with a maximum rotation of 1.3° at 28 V, which is lower than in previous studies, likely due to differences in system configuration, model, and material. Anyway, the proposed approach is suitable also for different optical systems (i.e., trinocular microscopes).
Enantioselective electroanalysis, which aims to discriminate the enantiomers of electroactive chiral probes in terms of potential difference, is a very attractive goal. To achieve this, its implementation is being studied for various "inherently chiral" selectors, either at the electrode surface or in the medium, yielding outstanding performance. In this context, the new inherently chiral monomer Naph2T4 is introduced, based on a biaromatic atropisomeric core, which is advantageously obtainable in enantiopure form without HPLC separation steps by a synthetic route hinging on enantiopure 2,2’-dibromo-1,1’-binaphthalenes. The antipodes of the new inherently chiral monomer can be easily electrooligomerized, yielding inherently chiral electrode surfaces that perform well in both cyclic voltammetry (CV) enantiodiscrimination tests with pharmaceutically interesting molecules and in magnetoelectrochemistry experiments.
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