A B S T R A C TThe objective of this work was to obtain the drying kinetic curves of white-fleshed 'pitaya' peels and characterize the obtained powder regarding physical and chemical parameters. Different mathematical models were fitted to the experimental data of drying kinetics, considering the coefficient of determination (R²), mean square deviation (MSD) and residual distribution as fit criteria. The peels had an initial moisture content of 93.38% (w.b.) and final moisture contents of 5.39% at temperature of 50 °C, 5.27% at 60 °C and 4.40% at 70 °C. After drying, the peels were disintegrated to obtain the powders and characterized for moisture content, reducing sugars, total titratable acidity, ascorbic acid, betacyanins, betaxanthins, water activity and color, in order to evaluate the influence of temperature on the quality of powders. The Page model was the one that best fitted to the experimental data, presenting coefficient of determination higher than 0.998, mean square deviation lower than 0.02 and random distribution of residuals. Increment in drying air temperature promoted increase of pH, ascorbic acid, luminosity and yellowness, and reduction of moisture content, reducing sugars, acidity, betacyanins, betaxanthins, water activity and redness. Considering the retention of betalains, the drying temperature of 50 °C is the most suitable for the production and use of 'pitaya' peel powder.Cinética de secagem e caracterização física e química de cascas de pitaya com polpa branca R E S U M O Objetivou-se com este trabalho obter as curvas de cinética de secagem das cascas de pitaya branca e caracterizar o pó obtido quanto aos parâmetros físicos e químicos. Diferentes modelos matemáticos foram ajustados aos dados experimentais de cinética de secagem, considerando-se como critério de ajuste o coeficiente de determinação (R 2 ), o desvio quadrático médio (DQM) e a distribuição dos resíduos. As cascas apresentaram teor de água inicial de 93,38% b.u. e final de 5,39% na temperatura de 50 °C, 5,27% em 60 °C e 4,40% em 70 °C. Após as secagens, as cascas foram desintegradas, para a obtenção dos pós e caracterizadas quanto ao teor de água, açúcares redutores, acidez total titulável, ácido ascórbico, betacianinas, betaxantinas, atividade de água e cor, com a finalidade de se avaliar a influência da temperatura na qualidade dos pós. O modelo de Page foi o que melhor se ajustou aos dados experimentais, apresentando coeficiente de determinação maior do que 0,998, desvio quadrático médio menor que 0,02 e distribuição aleatória dos resíduos. O aumento da temperatura do ar de secagem promoveu aumento do pH, ácido ascórbico, luminosidade e intensidade de amarelo e a redução do teor de água, açúcares redutores, acidez, betacianinas, betaxantinas, atividade de água e intensidade de vermelho. Considerando-se a retenção de betalaínas, a temperatura de secagem de 50 o C é a mais adequada para produção e utilização das cascas de pitaya em pó. Introduction'Pitaya' is a fruit belonging to the Cactaceae family, globally known as "...
Resumo O acuri é uma fruta pouco explorada industrialmente, mas com grandes perspectivas e possibilidades de uso. Para tanto, torna-se necessário reduzir o seu teor de água, aumentando então a sua vida útil, o que possibilitará sua utilização em mercados distantes dos locais de produção. Nesse sentido, objetivou-se secar fatias de acuri, com espessura de aproximadamente 4,07 mm, nas temperaturas de 60, 70, 80 e 90 °C, ajustar diferentes modelos matemáticos aos dados experimentais e determinar os coeficientes de difusão, a energia de ativação e as propriedades termodinâmicas. Observou-se que o aumento de temperatura de 30°C reduziu em 36% o tempo total de processo, sendo obtidas taxas de secagem máximas de 1,22; 1,88; 2,16, e 2,45 kg de água kg de matéria seca min-1 nas temperaturas de 60, 70, 80 e 90 °C, respectivamente. Dentre os modelos matemáticos testados, o modelo logarítmico apresentou os melhores parâmetros de ajustes aos dados experimentais e foi selecionado como o mais adequado para representar o fenômeno investigado. Os coeficientes de difusão efetivos aumentaram com o incremento de temperatura, apresentando-se na ordem de 10-10 m2 s-1 , e sua dependência com a temperatura foi descrita pela Equação de Arrhenius, que apresentou energia de ativação de 17,66 kJ mol-1 . Os valores de entalpia e entropia reduziram com a elevação da temperatura de secagem, enquanto que a energia livre de Gibbs foi ampliada na faixa de temperatura avaliada.
This study aimed to evaluate the effect of drying temperature (50, 60, 70 and 80 °C) on okra dehydration by comparing its powder’s physical properties obtained from a sample produced by a lyophilization process. Ten drying models were adjusted to the experimental data of the drying kinetics. As a result, effective diffusivity and activation energy were determined in addition to thermodynamic parameters: entropy, enthalpy and Gibbs free energy. A physical characterization, as well as the pigments and colorimetry analyses of the aforementioned powders were made, by comparing them with samples produced by lyophilization. The powders were characterized for hygroscopicity, solubility, wettability, apparent and compacted density, fluidity and cohesiveness, pigments, colorimetric, morphological analysis (SEM) and X-ray diffraction. Midilli model was the one that best adjusted to the drying kinetic curves. There was a booster in the effective diffusion coefficient with the increase of temperature. Enthalpy and entropy were reduced with the increase of both drying temperature and Gibbs free energy. The powders presented high luminosity, and the lyophilized powder had higher pigments retention and greater solubility. All powders presented poor fluidity and intermediate cohesiveness, with amorphous, irregular and asymmetric particles. Thus, from the present study it was possible to evaluate the best drying method, the one that should be applied for the drying of okra, considering the costs involved, its quality and the final application of the product, meeting the specific needs of each consumer
Citron watermelon is an agricultural product of excellent economic potential. Its seeds are widely used for oil extraction, serving as an energy source, showing nutritional characteristics that make them a suitable product to be studied. Thus, the objective was to characterize citron watermelon seeds regarding their physicochemical composition, in addition to determining drying kinetics, fitting mathematical models to the data, and determining the effective diffusivity coefficients and thermodynamic properties. The seeds were dried in a convective dryer, varying the drying temperature, with air velocity of 1.0 m s-1. With the increase in drying temperature, there were reductions in moisture content, water activity (aw), ash concentration, total titratable acidity, lipids and reducing sugar. Citron watermelon seeds are rich in lipids and ash, have low sugar concentration and low acidity; their drying kinetics was very well described by the Two Terms and Approximation of Diffusion models, followed by the models of Midilli and Page, which resulted in acceptable fits. Effective diffusivity accompanied the increase in drying temperature, and this behavior was well fitted by an Arrhenius-type equation. Enthalpy and entropy variations were reduced with drying temperature, with increments in Gibbs free energy.
The agricultural processing industry is continually working to meet consumer demand for new products, diversifying the supply of non-perishable items ready for consumption, conveniently prepared to maintain the main characteristics of the raw material. The objective of this work was to dehydrate whole okra by lyophilization and convective drying at 50, 60, 70 and 80 °C and to evaluate the influence of drying processes on the chemical and physical quality of powdered products. The powders had acceptable contents of lipids, sugars, proteins, pectin, chlorophyll and carotenoids, high hygroscopicity and low solubility. Lyophilization produced powders with characteristics closer to those of the fresh raw material. Regarding the contents of ashes, pectin, lipids and chlorophyll b, the samples obtained by convective drying showed characteristics close and even superior to those of the lyophilized powder.
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