Group formation in living systems typically results from a delicate balance of repulsive, aligning, and attractive interactions. We found that a mere motility change of the individuals in response to the visual perception of their peers induces group formation and cohesion. We tested this principle in a real system of active particles whose motilities are controlled by an external feedback loop. For narrow fields of view, individuals gathered into cohesive nonpolarized groups without requiring active reorientations. For wider fields of view, cohesion could be achieved by lowering the response threshold. We expect this motility-induced cohesion mechanism to be relevant not only for the self-organization of living systems, but also for the design of robust and scalable autonomous systems.

The formation and kinetics of grain boundaries are closely related to the topological constraints imposed on their complex dislocation structure. Loop-shaped grain boundaries are unique structures to establish such a link because their overall topological "charge" is zero due to their null net Burgers vector. Here, we observe that a local rotational deformation of a 2D colloidal crystal with an optical vortex results in a grain boundary loop only if the product of its radius and misorientation exceeds a critical value. Above this value, the deformation is plastic and the grain boundary loop spontaneously shrinks at a rate that solely depends on this product, while otherwise, the deformation is elastically restored. We show that this elastic-to-plastic crossover is a direct consequence of the unique dislocation structure of grain boundary loops. At the critical value, the loop is structurally equivalent to the so-called "flower defect" and the shrinkage rate diverges. Our results thus reveal a general limit on the formation of grain boundary loops in 2D crystals and elucidate the central role of defects in both the onset of plasticity and the kinetics of grain boundaries.

Understanding grain growth is key for controlling the microstructure and the mechanical properties of most polycrystalline materials, including metals, alloys, and ceramics. However, the precise mechanisms and kinetics of grain growth remain poorly understood both at the theoretical level and experimentally as direct observation is cumbersome in atomic systems. Here, we study the grain growth process in a polycrystalline monolayer of colloidal hard spheres. We find that the bond-orientational correlation function satisfies the dynamic scaling hypothesis and has the general scaling form predicted for systems containing random domain walls. However, the associated correlation length grows slower than ∼t 1=2 , which corresponds to normal curvature-driven grain growth. To understand the origin of this anomalous grain growth, we directly monitor the evolution of the grain boundary network by measuring the so-called grain boundary character distribution. We show that there is a strong annihilation of large-angle grain boundaries while small-angle grain boundaries become relatively more present. Using scaling arguments, we derive the time dependence of the correlation length and show its good agreement with the data. We conclude that the origin of anomalous grain growth is the curvature-driven coarsening of the large-angle grain boundaries at a rate that depends on their relative length in the total grain boundary network.

We investigate the segregation of impurities to grain boundaries in colloidal polycrystalline monolayers using video microscopy. A model colloidal alloy is prepared by embedding large spherical impurities in a polycrystalline monolayer of small host colloidal hard spheres, which stops grain growth at a finite grain size. The size ratio between the impurities and the host particles determines whether they behave as interstitial or substitutional impurities in the bulk crystal, akin to those in real alloys. We find that the partitioning of impurities between the grains and the grain boundaries is in very good agreement with the Langmuir-McLean adsorption model for equilibrium grain boundary segregation. This enables the direct measurement of the free energy of adsorption for the two types of impurities. Near saturation, we characterize the spatial distribution of the adsorbed impurities and find that it strongly depends on their interstitial or substitutional nature. This is because the relative importance of clustering and mixing due to nonadditivity is determined by geometrical constraints imposed by the crystalline host lattice.

We study the irreversible aggregation kinetics of superparamagnetic colloidal particles in two dimensions in the presence of an in-plane magnetic field at low packing fractions. Optical microscopy and image analysis techniques are used to follow the aggregation process and in particular study the packing fraction and field dependence of the mean cluster size. We compare these to the theoretically predicted scalings for diffusion limited and deterministic aggregation. It is shown that the aggregation kinetics for our experimental system is consistent with a deterministic mechanism, which thus shows that the contribution of diffusion is negligible.