Development of a 3D printable material system possessing inherent piezoelectric properties to fabricate integrable sensors in a single-step printing process without poling is of importance to the creation of a wide variety of smart structures. Here, we study the effect of addition of barium titanate nanoparticles in nucleating piezoelectric β-polymorph in 3D printable polyvinylidene fluoride (PVDF) and fabrication of the layer-by-layer and self-supporting piezoelectric structures on a micro- to millimeter scale by solvent evaporation-assisted 3D printing at room temperature. The nanocomposite formulation obtained after a comprehensive investigation of composition and processing techniques possesses a piezoelectric coefficient, d, of 18 pC N, which is comparable to that of typical poled and stretched commercial PVDF film sensors. A 3D contact sensor that generates up to 4 V upon gentle finger taps demonstrates the efficacy of the fabrication technique. Our one-step 3D printing of piezoelectric nanocomposites can form ready-to-use, complex-shaped, flexible, and lightweight piezoelectric devices. When combined with other 3D printable materials, they could serve as stand-alone or embedded sensors in aerospace, biomedicine, and robotic applications.

International audienceThrough an extensive and systematic experimental investigation of two geometries of flexible plates in air, it is shown that a properly defined scaled Cauchy number allows collapsing all drag measurements of the reconfiguration number. In the asymptotic regime of large deformation, it is shown that the Vogel exponents that scale the drag with the flow velocity for different geometries of plates can be predicted with a simple dimensional analysis reasoning. These predicted Vogel exponents are in agreement with previously published models of reconfiguration. The mechanisms responsible for reconfiguration, namely area reduction and streamlining, are studied with the help of a simple model for flexible plates based on an empirical drag formulation. The model predicts well the reconfiguration observed in the experiments and shows that for a rectangular plate, the effect of streamlining is prominent at the onset of reconfiguration, but area reduction dominates in the regime of large deformation. Additionally, the model demonstrates for both geometries of plates that the reconfiguration cannot be described by a single value of the Vogel exponent. The Vogel exponent asymptotically approaches constant values for small and for very large scaled Cauchy numbers, but in between both extremes it varies significantly over a large range of scaled Cauchy number. Copyright © Cambridge University Press 2010

The solvent-cast direct-write fabrication of microstructures is shown using a thermoplastic polymer solution ink. The method employs the robotically controlled microextrusion of a filament combined with a rapid solvent evaporation. Upon drying, the increased rigidity of the extruded filament enables the creation of complex freeform 3D shapes.